铕、铽双稀土苯甲酸配合物的合成和共发光性能研究.pdfVIP

（3 ）光电信息材料与器件 铕、铽双稀土苯甲酸配合物的合成 及共发光性能研究 陈雁，张静，张乐，韩朋德，王丽熙，张其土 （南京工业大学，材料科学与工程学院，江苏南京 210009 ） 摘要：以苯甲酸 （BA ）为第一配体、邻菲罗啉（phen ）为第二配体，合成了铕掺杂铽苯甲酸邻菲罗啉系列 配合物Tb Eu (BA) phen （x=0.01 、0.03 、0.05 、、0.07、0.09 、0.10、0.30 、0.50 ）。通过红外光谱、热分析、 1-x x 3 X 射线衍射、紫外吸收光谱和荧光光谱对稀土有机配合物的结构、热稳定性以及发光性能进行了研究。结 果表明，该系列配合物中 Tb3+ 离子对 Eu3+ 离子的发光具有强烈的敏化作用，系列配合物在 614nm 处均有 Eu3+ 的特征发射峰出现；同时，Tb3+ 在545 nm 处的特征发射峰没有被Eu3+ 淬灭，并且其强度随x 的减小而 增大，当x=0.01 时配合物的荧光强度达到最大；545 nm 和614 nm 处发射峰强度比值为1.73，实现了Eu3+ 、 Tb3+ 的共发光。调节两者之间的比例可以获得不同发光颜色的配合物。 关键词：有机高分子材料；光致发光；共沉淀法；荧光强度；共发光 Synthesis and co-luminescence properties of Eu-Tb multiple rare earth complexes with benzoic acid CHEN Yan, ZHANG Jing, ZHANG Le, HAN Pengde, WANG Lixi , ZHANG Qitu (College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009) Abstract: Series of rare earth complexes Tb Eu (BA) phen(x=0.01~0.10) were synthesized with 1-x x 3 BA as the first ligand and phen as the second ligand. The complexes were characterized by means of FTIR, TG-DSC, XRD, UV absorption spectra and photoluminescence spectra (PL). The results 3+ 3+ showed that the luminescent intensity of Eu in the complexes increased as Tb transfer the 3+ 3+ absorbed energy to Eu ion in the complexes . The emission of Tb at 545 nm was not quenched 3+ by Eu and increasing with x decreased. When x=0.01, the fluorescence intensity reached the 3+ 3+ maximal value as well as the emission intensity of Tb at 545 nm and E