疏水改性聚丙烯酰胺制备及在水处理中应用.pdfVIP

第十一届全国博士生学术年会 疏水改性聚丙烯酰胺的制备及在水处理中的应用 1,2 1 1 1 廖熠 戴力 关庆庆 郑怀礼 （1.重庆大学城市建设与环境工程学院，重庆，400045 ；2. 四川理工学院建筑工程学院，自贡，643000 ） 摘要：疏水改性聚丙烯酰胺(HMPAM)是疏水缔合水溶性聚合物(HAWSP) 中研究最多的一种,它可以通过在聚丙烯酰胺 (PAM) 中引入少量疏水基团而得到。由于疏水基团的憎水作用，共聚物水溶液中产生分子间缔合作用，从而具有独特 的流变性能。其在石油开采、涂料工业、生物医学、污泥处理及水处理等方面具有良好的应用前景。本文对制备 HMPAM 的聚合方法进行了综述, 主要包括共聚法和PAM化学改性法。并对HMPAM 的合成和在水处理方面的应用前 景进行了展望。 关键词：疏水改性聚丙烯酰胺；合成方法；应用；水处理 Hydrophobically Modified Polyacrylamide Synthesis and Application in Water Treatment Yi Liao1,2 Li Dai1 Qingqing Guan1 Huaili Zheng1 (1.Faculty of Urban Construction Environmental Engineering, Chongqing University, Chongqing, 400045，China；2 Department of Architectural Engineering, Sichuan University of science and engineering, Zigong, 643000, China) Abstract ：Hydrophobically modified polyacrylamide (HMPAM) is one of the most widely studied hydrophobically associating water-soluble polymers (HAWSP). It can be prepared by the incorporation of a small amount of hydrophobic groups into polyacrylamide (PAM). The intermolecular association within copolymer solution generated from the hydrophobic effect of hydrophobic groups cause special rheology character. It has good prospects in application of oil exploration，coating industry，biomedicine ，as well as sludge dewatering and water treatment，etc. The synthetic methods of HMPAM are reviewed. It mainly includes direct copolymerization and post polymerization. Based on these reviews, future research prospects relating to its synthesis and application in water treatment were proposed. Keywords：Hydrophobically modified polyacrylamide ；Synthesis method；Application ；Water treatment 近年来，疏水缔合聚合物由于其水溶液独特的流体力学性质，倍受科研工作者们的关注，广泛 地应用于石油开采、涂料工业、生物医学、污泥处理及水处理等领域[1-3] 。其中，疏水缔