有机硅KH_570改性硅溶胶杂化涂层的制备研究.pdfVIP

Vol1 38 No1 3 38 3 # 88# NEW CH EM ICAL MATERIALS 2010 3 KH-570 董洪亮 李国军 崔学军 任瑞铭 ( 大连交通大学辽宁省轨道交通关键材料重点实验室, 大连 116028) 以硅 胶C- 甲基丙烯酰氧丙基三甲氧基硅烷( KH-570) 为原料, 将低钠型碱性硅 胶经强酸性阳离子交换 树脂离子交换后, 得到酸性硅 胶, 将其与KH-570 按一定比例共混搅拌, 通过KH-570 在酸性条件下, 水解缩聚, 制得有 机/ 无机杂化 胶以低碳钢Q235 为基材, 制备出硅烷偶联剂KH-570( MEMO) 改性硅 胶的杂化涂层以FT-IR 测试 方法对其结构进行了表征, 采用动电位极化曲线测试涂层的耐蚀性能以光学显微镜SEM 观察涂层与碳钢裸片在腐蚀 前后的表面形貌研究结果表明: 酸性硅 胶与 KH-570 的水解缩聚产物通过共缩聚反应在碳钢表面形成带有有机基团 的无机交联网络, 基本骨架由Si-O-Si 组成, 经过 100 e 热处理, 即可得致密涂层, 涂层均匀透明, 无缺陷电化学分析表 明涂层形成物理屏障, 为基体提供了优良的腐蚀保护杂化涂层显现出良好的耐蚀性能 杂化涂层,硅 胶, KH-570, 耐蚀性 Preparation of hybrid coatings of silica sol modified by organosilicone KH-570 Dong Hongliang Li Guojun Cui Xuejun Ren Ruiming ( Liaoning Key M aterials Laboratory for Railw ay, Dalian Jiaotong U niversity, Dalian 116028) Abstract Acidic silica sol was prepared via ion exchange using alkalic silica sol w ith low sodium as raw materials. The organic/ inorganic hybrid sols w ere prepared by hydrolyzation and condensation in the solution of acidic silica sol using 3-methacryloxypropyl-trimethoxysilane ( KH-570 ) and silica sol as raw materials. Hybrid coatings w ere dip-coated on Q235 steel substrat es. The st ruct ure was characterized by FT-IR. The corrosion resistance of coatings was characterized by potent iodynamic polarization curve. The surface morphology of hybrid films was characterized by optical m icroscopy and SEM. The results showed that the base backbone was composed of Si-O-Si network structure . Hybrid coat ings w ere found to be relatively dense, uniform, transparent and defect free after annealing at 100 e @ 4h. Elect rochemical analysis show ed the hybrid coatings had good ant-i corrosion pro