非化学改性改善淀粉基材料物理性能及应用研究进展.pdfVIP

Research Progress on Improvement of the Physical Properties of Starch-based Materials by Non-chemical Modification Bingxin Sun, Chunyang Han, Zhiyong Wang, Baiqing Zhang, Xiangpeng Meng Food College, Shenyang Agricultural University, Shenyang, 110866 Email :sunbxin@ Abstract ：Because of the problems of aging and poor water resistance of the starch-based materials, the application of such materials are subject to many restrictions. By starch modification to prepare the materials and improve its‘ physical properties has drawn people‘s attention. Compared with chemical modification, non -chemical modification is more green, environmental and safe due to the feature of non residual solvents. In this paper, the choice of plasticizer system, incorporation of the hydrophobic additives and influence of different amylose content on properties are summarized to give the latest research progress through non-chemical modification of starch-based biodegradable materials to improve the physical properties. Key Words ：starch；plasticizer ；aging ；barrier of moisture 非化学改性改善淀粉基材料物理性能的应用研究进展 孙炳新，韩春阳，王志永，张佰清，孟祥鹏 沈阳农业大学食品学院，沈阳 110866 e-mail: sunbxin@ 【摘要】淀粉基材料由于存在老化变脆以及耐水性能差等缺点，使得该类材料的应用受到诸多限制。通过 将淀粉改性制备淀粉基生物降解材料并改善其物理性能，是目前淀粉材料的研发热点。与化学改性淀粉相比， 非化学改性不存在化学试剂的残留，具有―绿色‖―环保‖―安全‖等优点。本文从增塑剂体系的选择，疏水性添加剂 的应用以及直链淀粉含量对材料性能的影响三个方面，总结了国内外近年来通过非化学改性方法改善淀粉基生 物降解材料物理性能的最新研究进展。 【关键词】淀粉；增塑剂；老化；阻湿性 1 引言 由于淀粉之间强烈的氢键作用形成的结晶使淀粉 在过去的 50 年中，石油塑料和各种聚合物在包装 本身不具备热塑性，需要加入小分子塑化剂与淀粉之 上的应用增长是惊人的，据估计目前每年全球塑料的 间形成强烈的氢键，降低淀粉分子的结晶度，从而降 [1] 低淀粉的玻璃化转变温度，使淀粉表现出良好的热塑 消耗量约 2 亿吨，并且每年以 5%的速度递增 。