LF炉精炼废渣中含硫相形成机理研究.pdfVIP

LF 炉精炼废渣中含硫相形成机理研究 ·1 · LF 炉精炼废渣中含硫相形成机理研究 甘万贵 （武汉钢铁集团金属资源有限责任公司，武汉 430082 ） 摘 要 采用微观分析和热力学分析手段对 LF 精炼废渣物相析出过程和含硫相形成机理进行研究。在快速冷却 条件下LF 精炼废渣物相析出充分，物相析出顺序与其平衡温度有关，低熔点的铝酸钙物相以基体相形式析出。 渣中物相析出机理符合CaO-SiO -Al O 伪三元渣系相图研究结果。在物相析出过程中硫在基体相中富集，并在各 2 2 3 物相交界处与其它元素形成低熔点的混合渣相。在含硫渣相中，静电势较低的S2-与Ca2+形成CaS 离子对，并与 铝酸钙基体相发生置换反应，最终形成铝酸钙硫化物。 关键词 精炼废渣 微观分析 热力学 物相 硫 Sulf-phase Forming Mechanism in LF Refining Spent Slag Gan Wangui ( Metal Resources Co., Ltd. of Wuhan Iron Steel Group, Wuhan，430082) Abstract The process of the phase separated out of refining spent slag and the sulf-phase forming mechanism in the slag has been studied by means of micro- and thermodynamics analysis. In the conditions of rapid cooling, the phase is separated out from the slag completely, the forming sequence of phase is related to its thermodynamics equilibrium temperature, and the calcium-aluminate is formed as ground phase due to its lower melting temperature. The forming mechanism of phase in slag accords with the theory of CaO-SiO -Al O three-component phase diagram. The sulfur is enriched in the ground phase 2 2 3 during the process of phase separated out and, among the boundary of phases with other elements, it forms a complex 2 2 sulf-phase, which is not a single phase and its melting temperature is lower. The S - and Ca + with lower electrostatic potentia in the complex sulf-phase form CaS, which carries replacement reaction with the ground phase of