葡萄糖酸膨润土在PVA改性应用.pdfVIP

葡萄糖酸膨润土在PVA 改性中的应用 1 姜宏鹏，朱云倩，韦藤幼，潘远风，童张法 （广西大学化学化工学院，广西南宁，530004 ） 摘要：聚乙烯醇（简称PVA ）是一种多羟基高分子材料，由于其具有水溶性及生物相容性好等特 点而得到广泛应用，但是由于其耐水性差、强度低等不足限制了其范围。葡萄糖酸是一种多羟基 有机酸，用它碱性钙基膨润土反应可得到一种多羟基纳米有机膨润土。把这种纳米有机膨润土与 PVA 复合，制备了PVA/ 葡萄糖酸膨润土复合材料。通过考察PVA浓度、机械搅拌和超声震荡的搅 拌方式等因素，制得了分散均匀的PVA/ 葡萄糖酸膨润土纳米复合材料。通过实验测试，表明该 复合材料的拉伸强度相对于原材料提高了60%倍、耐水性提高了一倍。 关键词：膨润土，PVA ，改性，复合材料 中图分类号：TE626.24 文献标识码：A THE APPLICATION OF GLUCONIC ACID MONTMORILLONITE ON PVA MODIFICATION 1 Jiang Hong peng , Zhu Yun qian,Wei Teng you, Pan Yuan feng, Tong Zhang fa 1 ( College of Chemistry and Chemical Engineering, Guangxi University, Guangxi,Nanninge, China;530004) Abstract ：The polyvinyl alcohol is a kind of polyhydric high polymer material ，which has good water-solubility and biocompatibility has been in widespread use,however it’s poor water resistance and intensity which limits its application. Gluconic acid is a kind of polyhydric organic acid. which react with alkaline Ca-bentonite get a kind of nanometer organic bentonite. Which composite with PVA , get the PVA/glucose acid bentonite composite materials. Through the investigation of PVA concentration, mechanical agitation and ultrasonic agitation modes of concussion, etc. Get the uniform dispersion of PVA/glucose acid bentonite nanocomposite materials. Through the experiment test show that the tensile strength of the composite materials increase the relative to 60%, water-tightness raised one times. Key words ：bentonite ；PVA ；modification; composite materials 引 言 PVA( 聚乙烯醇) 是由聚醋酸乙烯酯水解而成的一种水溶性聚合物,其分子主链为碳链, 每一个重复单元上含有一个羟基, 由于羟基尺寸小,极性强,容易形成氢键, 因此 PVA 具有良 [1 ] ，但由于其耐水性差、 好的水溶性、成膜性、黏结力和乳化性, 良好的耐油脂性和耐溶剂性 强度低