过饱和铝酸钠溶液中Al(OH)3均相成核机理.pdfVIP

18 8 2008 8 Vol.18 No.8 The Chinese Journal of Nonferrous Metals Aug. 2008 1004-0609(2008)08-1560-06 Al(OH) 3 ( 410083) 323328 333 K1.33750~110 g/L 6~8−34~35 mJ/m2 1.5~2.0 µm 50.2 kJ/mol O643.12 A Mechanism of homogeneous nucleation in supersaturated sodium aliminate solutions ZHANG Li-chuan, CHEN Qi-yuan, YIN Zhou-lan (College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) Abstract: The homogeneous nucleation induction period of synthetic, optically clear caustic aluminate solution were investigated with the application of a self-made online conductivity analyzer. The experiments were performed at 323, 328 and 333 K and solution ratio of 1.337 with Na2Ok concentration in the range of 50−110 g/L. The results show that the nucleation kinetics are 6~8 orders dependence upon Al O relative supersaturation and strong temperature effect, the critical 2 3 interfacial energy is of 34−35 mJ/m2, the critical nucleus size is of 1.5−2.0 µm and the activation energy is of 50.2 kJ/mol. The mechanism of sodium aluminate solution nucleation is homogeneous and chemical reaction controlled. Key words: sodium aluminate solution; homogeneous nucleation; conductivity analyzer; online detection Al(OH)3 [1−2] 1