介质分配系数预测二恶英类物质潜在蓄积趋势研究.pdfVIP

第五届全国环境化学大会（2009） 介质分配系数预测二恶英类物质潜在蓄积趋势研究 董玉瑛 1* 赵盈丽 1 曹瑛 1 乔显亮 2 1 2 （大连民族学院环境工程系，大连，116605；大连理工大学环境与生命学院，大连，116024； *联系人，E-mail ：dong_yuying@163.com ） The international environment protection policy is to identify and control the sources of some chlorinated organic compounds including polychlorinated dibenzo-p-dioxins （PCDDs ） and polychlorinated dibenzofurans （PCDFs ）, often known collectively as dioxins. This study aimed to assess the transportation tendency of dioxins and predict locations at high risk for dioxin pollution. For this analysis, new parameter, compartment distribution coefficient （D ）, was created to account for the c tendency of dioxins to preferentially accumulate in particular compartments. It was obtained by proposed model combined with the mixture levels of PCDD/Fs in four countries: Japan, the United States, the United Kingdom, and Australia. The comparison with the temporal and spatial variation of Dc indicated whether the location release or long-range transportation caused the changes. It is good to understand some information relating to the pollution background of PCDD/Fs. It is also helpful to improve predicting accuracy of models introduced Dc to decrease uncertainties. This study showed that PCDD/Fs have the greatest tendency to remain in soil among studied media. Higher D value in Australia may indicate that this location c in Australia is a potential reservoir source of dioxins in the future. The results also appeared that problem of PCDD/F needs to b