煤结构化学的理论体系和方法论.pdfVIP

29 4 Vol. 29 No.4 2004 8 JOURNAL OF CHINA COAL SOCIETY A g. 2004 :0253- 9993(2004) 04- 0443- 05 曾凡桂, 谢克昌 ( , 030024) : 根据近年来煤科学的主要进展以及煤的基本特征, 对煤结构化学的概念理论体系及其 方 论进行了系统的论述. 指出煤结构化学的理论体系根据其任务可分为实验煤结构化学和计算 煤结构化学; 根据煤的层次结构特征, 煤结构化学可分为煤分子煤超分子和煤聚集态结构化 学. 煤结构化学的方 论应从煤的基本特征出发, 注重煤的多组成性以及它们之间的相互作用 煤的非晶态性结构的层次性以及煤演化的阶段性, 揭示煤结构特征与其物理化学性质关系的关 键是建立先进的煤结构化学概念. : 煤结构化学; 理论体系; 方 论; 煤的基本特征 : TQ530 : A Theoretical system and methodology of coal structural chemistry ZENG Fan-g i, XIE Ke-chang ( Key Laboratoryf or Coal Science Technology of Ministry of Education Shanx i Province , Taiy uan Univ ersity of Technology , Taiy uan 030024, China Abstract : Based on recent advances of coal science and the elementary characteristics of coal, the concept, theoretical system and methodology of coal str ct ral chemistry were disc ssed. According to the p rpose and task of coal str ct ral chemistry, it can be divided into two parts, i1e. experimental coal str ct ral chemistry, comp ting coal str ct ral chem- istry. According to the hiberarchy of coal, coal str ct ral chemistry incl des molec lar str ct ral chemistry of coal, s pramolec lar str ct ral chemistry of coal and aggregate str ct ral chemistry of coal. The methodology of coal str ct ral chemistry m st be b ilt on the gro nd of the elementary feat res of coal, which incl de the composition of s bstances in coal and their interaction, the amorpho s feat re of coal, the hiberarchy of coal and the stage evol tion of coal. The key to nderstand the relation of coal str ct re with the physica-l chemical properties is to constr ct an advanced concept of coal str ct ral che