TiAl合金防护涂层先驱溶胶的热分解和晶化过程.pdfVIP

24 Æ 5 Vol.24 No.5 2 0 1 0 10 CHINESE JOURNAL OF MATERIALS RESEARCH October 2 0 1 0 TiAl
      ( 110016) Y Æ, : 115 Æ, 180–280 , 380 , 440 Y O , 600 Y α–Y O 2 3 2 3 , Æ– , Y O , TG–DSC–MS, 2 3 TB304 1005-3093(2010)05-0483-04 Thermal Decomposition and Crystallization of Precursor Sol for Preparing Oxidation Resistant Coatings on Intermetallic TiAl TIAN Xiao JIA Qing∗ CUI Yuyou YANG Rui (Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016) Manuscript received February 1, 2010; in revised form May 19, 2010. * To whom correspondence should be addressed, Tel:(024 E–mail: qjia@imr.ac.cn ABSTRACT The thermal decomposition and subsequent crystallization process of Y sol after gelation were investigated by thermogravimetry–differential scanning calorimetry–mass spectrometry (TG–DSC– MS) coupling techniques, X-ray diffraction (XRD) and Fourier transform infrared spectrometry (FTIR). The results show that Y gel loses lots of organic solvents and free water at 115 . The hydroxyl con- densation between gel molecules takes place slowly from 180 to 280 . DSC curve of Y gel has two exothermic peaks in the range of 280–600 , which are contributed to the transformation from carboxy- late to subcarbonate at 380 and the formation of Y O crystallite from decomposition products of 2 3 subcarbonate at 440 . Y gel completely transforms into α–Y2 O3 at 600 . KEY WORDS inorganic