包渗工艺制备TiAl合金表面SiY共渗层的组织和抗高温氧化性能.pdfVIP

Trans. Nonferrous Met. Soc. China 25(2015) 803−810 Microstructure and high temperature oxidation resistance of Si−Y co-deposition coatings prepared on TiAl alloy by pack cementation process 1,2 2 2 Yong-quan LI , Fa-qin XIE , Xiang-qing WU 1. School of Materials Science and Engineering, Beifang University of Nationalities, Yinchuan 750021, China; 2. School of Aeronautics, Northwestern Polytechnical University, Xi’an 710072, China Received 31 March 2014; accepted 10 December 2014 Abstract: In order to improve the high temperature oxidation resistance of TiAl alloy, Y modified silicide coatings were prepared by pack cementation process at 1030, 1080 and 1130 °C, respectively, for 5 h. The microstructures, phase constitutions and oxidation behavior of these coatings were studied. The results show that the coating prepared by co-depositing Si−Y at 1080 °C for 5 h has a multiple layer structure: a superficial zone consisting of Al-rich (Ti,Nb) Si and (Ti,Nb) Si , an out layer consisting of (Ti,Nb)Si , a 5 4 5 3 2 middle layer consisting of (Ti,Nb) Si and (Ti,Nb) Si , and a γ-TiAl inner layer. Co-deposition temperature imposes strong influences 5 4 5 3 on the coating structure. The coating prepared by Si−Y co-depositing at 1080 °C for 5 h shows relatively good oxidation resistance at 1000 °C in air, and the oxidation rate constant of the coating is about two orders of magnitude lower than that of the bare TiAl alloy. Key words: TiAl alloy; Si−Y co-deposition coating;