超高效液相色谱质谱联用检测小麦中吡蚜酮的残留分析方法.pdfVIP

第54卷第1期 农药 Vol.54, No.1 2015年1月 AGR OCHEMICALS Jan. 2015 冯义志, 潘金菊, 刘伟. 超高效液相色谱质谱联用检测小麦中吡蚜酮的残留分析方法[J]. 农药, 2015, 54(1): 48-50. 超高效液相色谱质谱联用检测小麦中吡蚜酮的 残留分析方法 冯义志，潘金菊， 刘伟 济南250033) (山东省农药科学研究院山东省化学农药重点实验室， 摘要：[目的]建立吡蚜酮在小麦中的残留分析方法。[方法]样品经乙腈提取、净化后，质谱检测器检测。[结果]添加 质量分数为0.02~1 mg/kg时，吡蚜酮在小麦、土壤、麦苗和麦秆中平均添加回收率分别为78.7%~99.1%、72.3%~82.9%、 85.8%~91.4%和82.7%~93.9%，相对标准偏差分别为1.4%~7.8%、0.8%~2.7%、4.3%~9.2%和2.9%~4.3% 。吡蚜酮在 小麦中的最低检出质量分数为0.02 mg/kg。[结论]该方法快速简便，准确可靠。 关键词：吡蚜酮；小麦；残留 中图分类号：TQ450.2 文献标志码：A 文章编号：1006- 0413(2015)01- 0048- 03 Ana lysis of Pymetrozine Residue in Wheat by UPLC- MS/MS FENG Yi- zhi, PAN Jin- ju, LIU Wei (Key Laboratory for Chemical Pesticide of Shandong Province, Shandong Academy of Pesticide Sciences, Jinan 250033, China) Abstract: [Aims] The method for determining pymetrozine residue in wheat was developed. [Methods] The sample was extracted with acetonitrile, purified, and detected with MS. [Results] With the addition concentration of 0.02-1 mg/kg, the average recoveries of pymetrozine in wheat, soil, seedling and straw were 78.7-99.1, 72.3-82.9, 85.8-91.4 and 82.7-93.9% , the relative standard deviations were 1.4-7.8, 0.8-2.7, 4.3-9.2 and 2.9-4.3% , respectively. The limit of quantification for pymetrozine in wheat was 0.02 mg/kg. [Conclusions] The method is fast, simple, accurate and rel