有机蔬菜论文无公害蔬菜论文.pdfVIP

2010 12 20 12 Chinese JournalofHealth Laboratory Technology, Dec2010; Vol20 No 12 3185 蔬菜中有机磷农药气相色谱定量及指纹图谱定性方法 1 1 1 2 1 朱芸 ,赵清荣 ,雒婉霞,徐小明 ,杨勤德 ( 1. , 830011; 2. , 310000) [] : ( GC- FPD) FPD : , GC- FPD, FPD, : 0. 005mg/kg~ 0. 01mg/kg( S/N= 3), 67. 1 ~ 135 , 0. 9945~ 0. 9998: FPD,; , [] 蔬菜; GC- FPD;指纹图 + [] R155. 5 4 [] A [] 1004- 8685( 2010) 12- 3185- 02 Quantitative and qualitative analysis of phosphate pesticides by flame photometric detec tor in vegetablewith fingerprint 1 1 1 2 1 ZH U Yun , ZH A O Q in - g rong , L UO Wan -x ia , X U X iao -m ing , YAN G Q in -d e ( 1. XinjiangUygurAutonomousRegion Center forDisease Control and Prevention, Urumqi 830001, China; 2. ZhejiangCenter forDiseaseControl and Prevention, Hangzhou 310000, China) [Abstract] Objective: Gas chromatography with flame photometric detector ( GC- FPD) was reported in this paper to the quantitative determ ination of phosphate pesticide and qualitative analysiswith FPD fingerprint in vegetable. Methods: Samples were extractwith acetonitrile and purified through EnviCarb column. Specific FPD fingerprint of one kind of vegetable could be used forqualitativeanalysisthrough comparisonw ith standarcontrol. Results: The detection lmi itswerebetween0. 005mg/kg ~ 0. 01mg/kg( S/N= 3). Overall recoverieswerebetween 67. 1 ~ 135 .Thecorrelation coefficients for the linearequationswere 0. 9945~ 0. 9998. onclusion: Thequantitation ofphosphatepesticide could be determ ined by externalstandard and its recovery rates in some vegetableswere very good. [Keywords] Vegetables; GC- FPD; Fingerprint , 10 g/m l ,