焦化脱硫废液回收副盐转化与探讨.pdfVIP

焦化脱硫废液回收副盐转化的探讨 徐刚 李士琦 陈海勇 汤志刚 （北京科技大学冶金与生态工程学院，清华大学化学工程系，北京，100083） 摘要：随着国家环保法规定日趋严格及社会的环保意识不断增强，焦化厂焦炉煤气中 H 2 S 、HCN 及燃烧产物对大气环境的污染问题引起人们的广泛关注，甚至影响到焦化行 业的可持续发展，所以，对焦炉煤气进行脱硫脱氰净化处理势在必行。但是却带来了脱硫废 液处理问题。 本文通过对当前脱硫废液回收副盐的处理现状的分析，在 HPF 法脱硫废液提取的副盐 基础上，拟提出两条转化路径：制备硫氰酸钠和异构化硫脲，以提高焦化企业综合效益，降 低环境污染。 关键词：焦化 脱硫废水 HPF 法 NHSCN 异构化 The Discussion of the Transformation of Deputy Salt Recycled from Coking Desulfurizing Waste Liquor Xu Gang Li Shiqi Chen Haiyong Tang Zhigang (School of Metallurgical and Ecological engineering, University of Science and Technology Beijing, Department of Chemical Engineering, Tsinghua University, Beijing 100083) Abstract: As the states environmental regulations has been increasingly strict and social awareness of environmental protection has been continuously strengthened, the atmospheric environment pollution problems, caused by H 2 S , HCN and coke oven gas combustion products from the coking plant, aroused wide concern, which even affected the coking industrys sustainable development. Therefore, the purification and processing of coke oven gas desulphurization and decyanation is imperative. But how to deal with the desulfurization wastewater is a question. Based on analysis of current COG deputy salt recovery status of the treatmen and the deputy salt extracted from the HPF method , two conversion paths are proposed:To prepare the sodium thiocyanate and isomerization of thiourea ,which will increase coking enterprises comprehensive benefits and reduce environmental pollution. Key words: coking desulfurization wastewater HPF method NHSCN isomerization 1.引言 中国钢铁行业的迅猛发展，对焦炭的需求量日益增长，焦炭是通过焦化企业炼焦来生产 的，焦化企业在炼焦过程中，原料煤中的部分硫转化成H 2 S 等硫化物，与NH 3 和HCN 等 一起形成煤气中的杂质，H 2 S 和HCN 具有很强的腐蚀性、毒性，焦炉煤气用作