Application of a Step-by-Step Fingerprinting Identification Method on a Spilled Oil Accident in the Bohai Sea Area.pdfVIP

Application of a Step-by-Step Fingerprinting Identification Method on a Spilled Oil Accident in the Bohai Sea Area.pdf

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Application of a Step-by-Step Fingerprinting Identification Method on a Spilled Oil Accident in the Bohai Sea Area.pdf

OceanUniv.China OceanicandCoastalSeaResearch D0I10.1007/s1l802—011一l716—6 ISSN 1672—5182,201110 1 :35—41 http://www.oucedu.cn/x63,wb/ E—mail.xbyv~’b@ouc.educn ApplicationofaSteplb StepFingerprintingIdentification M ethodonaSpilledOilAccidentni theBohaiSeaArea SUN Peiyan。 , GAOZhenhui,CAOLixin,WANGXinping,ZHOUQing, ZHAOYuhui,andLIGuangmei l KeyLaboratoo’ofMarineSpillOilIdentfiicationandDamageAssessmentTechnology,SOA,Qingdao 266000,P.R China 2 NorthChinaSeaEnvironmentalMonitoringCentelofStateOceanicAdministration,Qingdao266000,P.R.China ReceivedSeptember25,2009;revisedJanuary3,201O:acceptedApril28,2010 @ OceanUniversityofChinaandSpringer—VerlagBerlinHeidelberg2010 Abstract Inrecentyears.oilspillaccidentsoccurrfequentlyinthemarineareaofChina.Findingoutthespilledoilsourceisakey stepintherelevantinvestigation.Inthispaper,astep_by—stepfingerprintingidentificationmethodwasusedinaspilledoilaccident intheBohaiSeain2002.Advancedchemicalfingerprintinganddatainteprretationtechniqueswereusedtocharacterizethechemical compositionanddeterminethepossiblesourcesoftwospilledoilsamples.Theoriginalgaschromatography flameionizationdetec— tion GC—FID chromatogram ofsaturatedhydrocarbonswascompared.Tilegaschromatography—massspectrometry GC/MS chromatogramsofaromatichydrocarbonsterpaneandsterane,n—alkaneandpoly—aromatichydrocarbonsfPAHs wereanalyzed.The correlationanalysisondiagnosticratioswasperfomr edwithStudent’st-testItisofundthattheoilfingeprrintingofthespilledoil fdesignatedassz1 from thepollutedsandbeachwasidenticalwiththesuspectedoil designatedaskv1 rfomanearbycrudeoiI refinery factory.Theybothshowedthefingeprrintingcharacterofmixedoil.Theoilfingerprintingofthespilledoil designatedas msI1collectedfrom theportwassignificantlydilyerentrfom oilkv1andoi1sz1andwaswithalubricatingoilfingeprrintcharacter. Theidentificationresultnotonlygavesupportforthespilledoilinvestigation.butalsoservedasanexampleofrstudyingspilledoi1 accidents. Keywords step—by—stepfingerprintingi

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