羟基铬柱撑二硫化钼的制备和其对苯加氢反应的催化活性.pdfVIP

27 12 2006 12 Vol. 27 No. 12 Chinese Journal of Catalysis December 2006 : 0253-9837(2006) 12- 1133-06 : 1133~ 1138 张进飞, 林碧洲, 孙东亚, 许百环, 丁 聪 ( 华侨大学材料物理化学研究所, 福建泉州362021) : [ Cr ( OH) ( H O) ] 6+ , 11 319~ 11341 nm 4 6 2 10 . X , 70 e 4 d ; , n ( Cr) / n( Mo) Cr3+ . 2H-MoS , 2 , , . , Cr-MoS 2 2H-MoS Raney Ni , . 2 : ; ; ; ; : O643 : A Preparation of Molybdenum Disulfide Composite Pillared by Hydroxy-Chromium Oligocations and Its Catalytic Activity for Ben ene Hydrogenation ZHANG Jinfei, L IN Bizhou* , SUN Dongya, XU Baihuan, DING Cong ( Institute of M aterials Physical Chemistry, H uaqiao University , Quanz hou 36202 , Fuj ian, China) Abstract: The molybden m dis lfide composite material pillared by hydroxy-chromi m oligocations [ Cr ( OH) - 4 6 6+ (H O) ] w ith the basal interlayer space from 11319 to 1134 1 nm w as prepared by intercalating the hydroxy 2 10 oligocations into the interlayers of molybden m dis lfide sing the single-molec lar-layer technology. X-ray diffraction show ed that the hydroxy-chromi m oligocations can be sed as a stable pillaring agent after aging at 70 e for fo r days,