醛_酮催化氨化合成吡啶和其烷基衍生物研究进展.pdfVIP

30 5 现代化工 M ay 2010 2010 5 Modern Chem ical Industry 21 - 冯 成, 张月成, 赵继全 (河北工业大学化工学院, 天津 300130) : -()- , , , , , : ; ; ; ZSM- 5; ; : Q217 : A : 0253- 4320( 2010) 05- 0021- 04 Progress in synthesis of pyridine and its alkyl derivatives by catalytic ammonization of aldehyde or ketones FEN G Cheng, ZHAN G Yuecheng, ZHA O J iquan ( School of Chem ical Engineering and echnology, H ebeiUn iversity of echnology, ianjin 300130, Ch ina) Abstract: Pyrid ine and its alkyl derivatives, w hich are socalled pyridine bases, are m ainly produced through catalytic amm on ization of aldehydeketones in industry. he m echan ism for the synthesis of pyridine bases and the catalyst are introduced, the reasons for low selectivity for pyridine bases and low lifetmi ew ith am orphous alum inosilicate as the catalyst are elaborated. It is found that the catalytic performance of am orphous alum inosilicate or shapeselective zeolite can be mi proved by m od ification th rough otherm etals. he acid ity of the shapeselective zeolite has a significant influence on the product d istribution. he acidity of the catalyst can be regu lated by changing the silicaalum ina ratio, and then the selectivity of pyrid ine bases can be increased. Keywords: pyrid ine; pyrid ine bases; catalyst; ZSM5; zeolite; alum inosilicate , ; , [ 1- 2] 1876 , 20 , - [ 3] 20 , , , -