双_2_4_二氯_6_羰丁烷氧苯基_草酸酯的合成和发红光体系的研究.pdfVIP

9 553 ( 2, 4- -6- ) * , , ( , 100037) : 合成了中间产物 3, 5- 二氯水杨酸 丁酯, 讨论了反应过程中催化剂和溶剂的影响, 产率为 98% 合成了化学 光母体双( 2, 4- 二氯- 6- 羰 丁烷氧苯基) 草酸酯, 产率为60% , 鉴定了其结构对 所合成的草酸酯 红光化学 光体系进行了研究, 分别考察了过氧草酸酯, 荧光剂, 催化剂, 氧化剂 及溶剂对 光时间和强度的影响, 确定了最佳配比, 光时间达6 h : 3, 5- 二氯水杨酸 丁酯; 双( 2, 4- 二氯- 6- 羰 丁烷氧苯基) 草酸酯; 合成; 化学 光; 光体系 : O 623. 624; O 644. 17 : A : 0367-6358( 2007) 09- 553- 04 Study on Synthes s of B s( 6-butoxycarbonyl-2, 4-d chlorophenyl) oxalate Ester and Its Red Em ss on Chem lum nescence Syst em * XU M n , DU Ha-yan, SUN J a-yue ( Chemical and Environmental Engi neering College , Beij ing Technology and Busi ness University , Beji i ng 100037, China) Abstract: The ntermed ate compound butyl 3, 5- d chlorosal cylate ester was synthes zed. The effects of catalyst and solvent on synthes s were stud ed. The y eld was 98% . B s ( 6-butoxycarbony-l 2, 4- d chlorophenyl) oxalate ester as an energy source was synthes zed and conf rmed. The y eld was 60% . Var ous factors affect ng the l ght l fe and the l ght ntens ty of the chem lum nescence system such as peroxyoxalate ester, fluorescence agent , catalyst , ox dant and solvent were also nvest gated .The opt mum formulat on was obta ned, and the system chem lum nescence l fe t me was 6 h. Key words: butyl 3, 5- d chlorosal cylate ester; b s ( 6- butoxycarbonyl-2, 4- d chlorophenyl ) oxalate ester; synthes s; chem lum nescence; chem lum nescence system , , , , , , [ 1] , , , , , , , ,