X射线粉末衍射少量试样试样板制作.pdfVIP

X ( , 200433) :从对参与衍射的试样体积( 宽度)入射X 射线在试样表面的总光量和亮度及X 射线被 试样吸收三 个方面在扫 过程中的变化的分析出发, 讨论了在试样量少到不能以薄层填满整 个试 样槽时, 如何制作试样板以得到衍射强度高的高质量衍射谱的方法在固定发散狭缝宽度的条件 下,为使参与衍射的试样面积大,使长度方向的试样尺寸与X 射线管中线焦点的长度相同比试样 宽度等于试样槽宽度更有利于得到较高的衍射强度但参与衍射的试样体积会在高角时随增 加而减少如用可变狭缝,则在全扫 过程中, 全部试样始终参与衍射, 衍射强度更高,但入射光光 通量随增加而增加如改用细条状试样及不需扫 的德拜谢乐或纪尼叶衍射几何,则入射光光 通量和参与衍射的试样体积均不随角变化 :X 射线粉末衍射仪; 试样板; 制作; 少量试样 :O434. 1 : A :2011 Specimen Plate Preparation for a Little Amount Specimen in Xray Powder Diffraction MA Lidun (Centre for Analysis and Measure ent, Fudan U niversity, Shanghai 200433, China) Abstract : For getting a high quality Xray powder diffraction pattern having higher diffraction intensity when there is only a little speci en which is not enough to spread a fil in a speci en groove on a speci en plate, the preparation of a speci en plate was discussed. The discussion was based on the analysis of the change of speci en volu e ( width) taken part in diffraction, Xray flux and brilliance on speci en surface, Xray absorption by speci en in scanning. Under the condition of the width of divergence slit ( DS) is fixed, for getting the largest speci en area taken part in the diffraction that the speci en size on the direction of length equals the length of the line focus in Xray tube is better than that the speci en size on the direction of width is equal to the width of the speci en groove. But in this casethe speci en volu e ( width) taken part in diffraction decreasewith the increase of in the range of high . If the slit is adjustable, the whole of the speci en in the speci en groove always takepart in the diffraction. T hereforethe diffraction intensity is higher. But the flux of inciden