以金属有机胺做模板具有纳米尺度的沸石(英文).pdfVIP

VOLUME 19, NUMBER 6 MARCH 20, 2007 ? Copyright 2007 by the American Chemical Society Communications Nanosized Zeolites Templated by MetalAmine three-dimensional channel system defined by the apertures Complexes of two different types of eight-membered rings mean diameters of 2.8 3.8 ? and 2.0 3.1 ? . The EDI-type J. Kecht,? S. Mintova,*,? and T. Bein*,? molecular sieve with nanosized dimensions is essential for preparation of hierarchical porous structures and thin films Department of Chemistry and Biochemistry, Uni ersity of with high water and ion-exchange capacities. Munich LMU , Butenandtstr. 11 E , 81377 Munich, Germany, and Laboratoire de Mate′riaux a` Porosite′ The microporous nanosized crystals were synthesized from contro? le′e, UMR 7016 CNRS, 3 rue Alfred Werner, solutions with the following chemical composition: 2.37: 68093 Mulhouse, France 0.05:1:4.16:244:0.5:15 TMA O/Na O/Al O /SiO /H O/ 2 2 2 3 2 2 TM O/NH3; TM is the transition metal, that is, Cu2, Pd2, Recei ed December 21, 2006 Pt2, Ni2, Co2, and Zn2. The metal nitrate salts, aluminum Re ised Manuscript Receied January 29, 2007 isopropoxide, Ludox HS-30 Silica, and TMAOH penta- Organic molecules containing quaternary ammonium hydrate used as reagents for preparation of all samples were groups are widely used as structure directing agents for obtained from Aldrich. For the synthesis of Cu-containing stabilization of certain framework type structures possessing molecular sieves, several solutions were prepared and variable porosity.1 Besides, the organic additives alter the abbreviated as follows: without NH3 Cu-1 , without Cu N- degree of super-saturation in the initial precursor solutions 2 , without Cu and NH3 Y-0 , and with different amounts and direct the formation of stable nanocrystallites in colloidal of Cu CuN-3 and CuN-4; see Table 1 . The precursor form.2 Templating of molecular sieves