负载型纳米铁吸附剂去除饮用水中As_的研究_朱慧杰.pdfVIP

30 6 　　　　　　 Vol.30, No.6 2009 6 Jun., 2009 NVIRONM NTAL SCI NC As(Ⅲ) 1, 2 1 ＊ 1, 2 1, 2 , , , (1., 　110016;2., 　100049) :, , (Fe )82.0 mg g. , 30 ～500 nm, 1 000～ 3000 nm.pH 6.5, (25±2)℃, As(Ⅲ)2 mg L, 1.0 g L, As(Ⅲ)99.86%, 1.997mg g;12 h , 94.3%, 72 h 3- 2- 2- 2- 2- .As(Ⅲ).PO 、SiO As(Ⅲ), SO 、CO 、C O 4 3 4 3 2 4 .0.1 mol L NaOH , ., . :;;As(Ⅲ);; :X52　:A　:0250-3301(2009)06-1644-05 Removal of Arsenite from Drinking Water by Activated Carbon Supported Nano Zero-Valent Iron 1, 2 1 1, 2 1, 2 ZHU Hui-jie ,JIA Yong-feng ,WU Xing ,WANG He (1.Key Laboratory ofTerrestrial cologicalProcess, Institute of Applied cology, Chinese Academy of Sciences, Shenyang 110016, China;2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China) 2+ Abstract:Nano zero-valent ironwas loaded onto activated carbon by deoxidizing Fe in aqueous solution and approximately 8.2%(wt)of iron was loaded it.The size of the needle-shaped iron particles in the pores of carbon was (30-500)×(1000-3000)nm.The adsorption capacity for arsenic was approximately 1.997 mg g activated carbon supported nano zero-valent iron (NZVI AC)in the 2 mg L As(Ⅲ)solution at pH 6.5 and (25±2)℃.The uptake of arsenic by NZVI AC was rapid in the first 12 h (94.3%)and equilibrium was achieved at 72 h (99.86%).As(Ⅲ)waspartly oxidized by the absorbent inthe process of absorption.The presence of phosphate andsilicate ions significantly decreased arsenic removal rate while the effect of other common ions such as sulfat