iData_高碘酸氧化法快速测定进口粗甘油中甘油含量_蒋小良.pdfVIP

22 3 Vol. 22No. 3 23 2013 5 CHEMICAL ANALYSIS AND METERAGE May 2013 doi 10.3969j.issn.1008–6145.2013.03.006 * 1 2 1 3 3 1 1 1 (1. 529000 2. 523000 3. 529000) 建立了高碘酸氧化法快速测定进口粗甘油中甘油含量的分析方法。对高碘酸钠加入量、溶液pH 值和放 置时间等主要影响因素进行了考察。经试验确定了最佳实验条件：质量浓度为60 g ／L 的高碘酸钠溶液加入量35 n mL ，pH 值在0.4～1.6 之间，放置时间40 min 。在选定实验条件下，该方法测定结果的相对标准偏差为 1.26% （=7 ）， 加标回收率为97.2% ～104.1%。 甘油；高碘酸氧化法；快速测定；粗甘油 O657.1 A 1008–6145(2013)03–0023–03 Rapid Determination of Glycerine in Imports of Crude Glycerine by Periodic Acid Oxidation Method 1 2 1 3 3 1 1 1 Jiang Xiaoliang Wang Bin Jia Changsheng Yu Jian Song Jindong Xu Zhenghua Chen Kai Sun Lu (1. Jiangmen Entry–Exit Inspection and Quarantine Bureau Jiangmen 529000 China 2. Dongguan Entry–Exit Inspection and Quarantine Bureau Dongguan 523000 China 3. Jiangmen HongJie Fine Chemcal Industry Co. Ltd Jiangmen 529000 China) Abstract A method for rapid determination of glycerine content in imports of crude glycerine by periodic acid oxidation method was developed. The main factors to influence determination of glycerine content by periodic acid oxidation method were studied which included amount of 60 gL NaIO4 pH and storage time. Under the optimized n conditions the relative standard deviation of detection results was 1.26% ( =7) and the recovery ranged from 97.2% to 104.1%. Keywords glycerine; periodic acid oxidation method; rapid determination; crude glycerine