甲苯一段半间歇硝化工艺的反应失控研究.pdfVIP

2007 06 INITIATORS PYROTECHNICS 2007 3 1003-1480 2007 03-0018-05 1 2 3 RC1e RC1e RC1e TQ565 A Runaway Evaluation of Semi-batch Toluene Mononitration in RC1e WANG Xiao-feng 1 CHEN Wang-hua 2 XUE Yan 3 1. Civil Aviation University of ChinaTianjin300300 2. Nanjing University of Science and TechnologyNanjing 210094; 3. National Defense Key Laboratory of Pyrotechnical SR ResearchXi’an710061 Abstract By adding toluene into the reactor filled with mixed acid, the thermochemistry and thermodynamics parameters of semi-batch reaction were measured which can be used for safer operation design. A series of toluene nitration experiments were carried out in an isothermal reaction calorimeter (RC1e) to study the influences of different operating conditions such as stirring speed, feeding rate and setting temperature and so on . The thermal hazard assessment of toluene nitration was derived from the measured calorimetric data, the adiabatic temperature increase( Tad) and maximal temperature attainable(MTSRmax) in a runaway situation can also be derived. Results indicate that the severity of a loss of control for mononitration of toluene by mixed acid can be reduced from medium to low by using semi-batch reactor, the MTSRmax under setting operating conditions are all in the range that can be accepted by the industrial nitration, so the reaction has less hazard potential by using those setting conditions. Key words Toluene mononitration; RC1e; Semi-batch reaction; Safe op