中心金属原子对萘酞菁化合物激发态的光学非线性增强效应（英文）.pdfVIP

第 44卷第 2期 红外与激光工程 2015年 2月 V01．44NO．2 InfraredandLaserEngineering Feb．2015 Centralmetalion enhancestheexcited stateopticalnonlinearity 0fnaphthal0cyaninecompound ChangQing，ChangCun，KongDegui，GaoYachen，GaoMeiling (CollegeofElectronicEngineering，Heilon~iangUniversity，Harbin150080，China) Abstract：The third—orderopticalnonlinearitiesof lead and palladium naphthalocyanine compoundswere studied comparatively using Z-scan technique with nslaserpulsesat532nm ．The experimentalresults showed thatthe two kinds of naphhtalocyanine compounds also indicated strong nonlinera absorption (reservesaturableabsorption)andnonlinearrerfaction (self—focusing)chraacteristics．Nonlinera absoprtion coefficient／3forleadnadpalladium naphhtalocyaninecompoundsbyhteroeticalfiuingwere6．54x10一mm／W and 3．90xl0一 m ／W ，reprectively．Nonlinera rerfactive index coeffi cientn2were 1．68xl0一m esu nad 8．04xlO一 esu，reprectively．The second—ordermoleculra hypeprolarizabilities were3．44x10一器esu and 2．57xl0～ esu．reprectively，which were approximately about10 orderin magnitude thna thatofCS2 r4．32xl0～esu)．Theexperimentalresultsshow thattheleadnaphthalocyaninecompoundexhibitsgreat opticalnonlinearitiesthan palladium naphthalocyanine compound resultsfrom the heavy metalatom sas centralatom ofnaphhtalocyanine lead compoundsenhance the opticalnonlinearitiesofnaphhtalocyanine compounds． Keywords：third—orderopticalnonlineraity； naphthalocyanine； heavyatom effect CLC number：0437 Documentcode：A ArticleID：1007—2276(20lS)02—0466—05 中心金属原子对萘酞菁化合物激发态的光学非线性增强效应 常 青，常 存 ，孔德贵，高亚臣，高关玲 (黑龙江大学 电子工程学院，黑龙江 哈尔滨 150080) 摘 要 ：应用 z一扫描技术对比研 究了萘酞菁铅和萘酞菁钯化合物在波长为532nm纳秒激光脉冲作 用下的三阶非线光学特性。实验结果表明，两种萘酞菁