尿素生产装置回收工艺的改进.pdfVIP

　Aug. 2004 现代化工 第 24 卷第 8 期 ·52 · Modern Chemical Industry 2004 年 8 月 尿素生产装置回收工艺的改进 莫彩利 　刘 　亮 　张红伟 (河南省中原大化集团有限责任公司 ,河南 濮阳457004) 摘要 : 中原大化集团公司52 万t/ a 尿素生产装置存在解析塔处理能力不足 ,碳铵液储存容积小 , 中压放空尾气中氨含量高 , 装置开停车时废水 、废气排放量大等问题 。通过拆除解析塔塔板并在塔内填充不锈钢规整填料 ,增设碳铵液储罐及吸收塔 ,改 进操作方法等措施 ,解决了上述问题 。中压放空尾气中氨质量分数由改造前的20 %降至 5 %以下 ,尿素氨耗降低约 1. 4 kg/ t ,并 使废水 、废气的排放得到了彻底改善 。 关键词 :尿素装置 ; 回收工艺 ;技术改造 ( ) 中图分类号 :TQ02817 ;TQ44141 　 文献标识码 :A 　 文章编号 :0253 - 4320 2004 08 - 0052 - 03 Recovering process modif ication of urea production unit MO Caili , L I U L iang , ZHAN G Hongwei (Zhong Yuan Dahua Group Ltd. of Henan Province , Puyang 457004 , China) Abstract : The urea production unit with its capability of 0 . 52 Mt/ a in Zhong Yuan Dahua Group Ltd. of Henan Province had such problems as low capability of the desorbers ,limited volume of depositing ammonium carbonate ,high content of ammo nium in blowdown tail gas of the medium pressure system ,and large quantity of waste water and waste gas discharged when the unit was opened and closed ,which were resolved by removing the column plate installed in the desorbers and filling regular packing made of stainless steel ,besides ,an ammonium carbonate liquid storing cistern and a absorber were added and operating step s improved. The mass fraction of ammonium in blowdown tail gas of the medium pressure system was decreased from 20 % to 5 % ,ammonium consumption was decreased by 1.