微波萃取GCMS法测定塑料制品中的六溴环十二烷.pdfVIP

微波萃取／GC．MS法测定塑料制品中的六溴环十二烷 Determinationof inPlasticProducts Hexabromocyclododecaneby MicrowaveExtraction／GC．MSMethod 。摘要： 一立了采用徽波萃取／气相色谱·质谱(GC-MS)法检一生科镧品中六澳环十二姨的方法。将破碎后的样晶 用正已槐7丙■(1：1)湛含溶搠进行徽波萃取。萃取液经硅胶小柱净化．平行纛麓定■浓缩后采用GC-MS法潮 定含量，外标法定量。优化了样昌村处疆囊件．包括前处曩方式的遗蝈k微波萃囊溶捆和萃取时闻的选择． 000 以及净化小柱的选择。对于六氇环十二烷标准溶液．在50-1 mg／L范■内。缀性关系良好。相关系数大干 O．999l方法定量一定下限为100 ■作俺便．分析迅遮．结果准确。可以囊足对塑料产昌中六疆环十=棘的定性和定量分析。 9Abstract：Anewmethodwasestablishedforthedeterminationof method．The in microwaveextraction withGC·MS plasticproductsby techniquecombining wascrushedandthen with solventlnmicrowave sample extractedhexane，acetone(1：1)mixed extraction at80 ℃for2h．Theextractwas withsilicasolid extraction equipment purifled geI phase then cOncentratedwith cartridge，andquantjtatjveIy paralleIevaporation theextraction extractiontime pretreatmentcondition，includingmethod。extractant，microwave andS；PE was the anddetection cartridgeoptimized．Underoptimumseparation wereconfirmedanddeterminedwithexternaIstandardmethod．ThestandardcurvesofHBCD solutionwereIinearintheconcentrationof50-1000 withcorrelationcoefficientmore range mglL therelative than0．999．Therecoveriesfrom81．3％to104％．with standard ranged of2．1％-5．8％．TheIowerIimitdetermination100 methodwas of fLDL)wasm