环戊烷萃取精馏脱硫实验动态研究.pdfVIP

化 工 进 展 2010 年第 29 卷第 1 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·173 · 研究开发 环戊烷萃取精馏脱硫实验动态研究 1 1 2 张娇静 ，柳艳修 ，张文超 1 2 （ 大庆石油学院化学化工学院，黑龙江 大庆 163318 ； 大庆石化工程有限公司工艺室，黑龙江 大庆 163000 ） 摘 要：提出了氢氧化钠溶液作为萃取剂对环戊烷进行萃取精馏脱硫的方法。考察了碱液浓度、剂油比、回流比 及助溶剂对脱硫效果的影响。实验结果表明其最佳脱硫条件为：有提馏段，以 4%的氢氧化钠溶液作萃取剂，剂 油比为4 ∶3 ，回流比为1 ∶5 ，环戊烷的硫含量最低为0.13mg/L ，脱硫率最高可达到97.8%。 关键词：环戊烷；萃取精馏；脱硫；剂油比；回流比 中图分类号：TE 991 文献标识码：A 文章编号：1000 –6608 （2010 ）01 –0173 –05 Experimental and dynamic research on the extractive distillation desulfurization of cyclopentane 1 1 2 ZHANG Jiaojing ，LIU Yanxiu ，ZHANG Wenchao 1 ( College of Chemistry and Chemical Engineering ，Daqing Petroleum Institute，Daqing 163318 ，Heilongjiang ，China ； 2 Process Office ，Daqing Petrochemical Engineering Co. Ltd. ，Daqing 163000 ，Heilongjiang ，China) Abstract: An extraction distillation desulfurization for cyclopentane is proposed when using sodium hydroxide solution as the extractant. Effects of alkali concentration ，the ratio of catalyst to oil ，reflux ratio and assistant solvent on the desulfurization are discussed. Results showed that the sufur content reduced to the lowest of 0.13mg/L ，where the desulfurization ratio reached to 97.8% under the optimal conditions. The optimal conditions are composed of a column in the stripping section，4% of sodium hydroxide concentration ，4 ∶3 of catalyst to oiland 1 ∶5 of flux ratio. Key words: cyclopentane; extraction distillation; desulfurization; solvent to oil