过氧化氢水溶液中过氧化氢含量分析的简便方法.pdfVIP

38 7 - Vol. 38 No.7 2002 7 PTCA ( PART B: CHEMICA ANA YSIS) July 2002 * , , , ( , 430074) : 用氧化还原滴定法测过氧化氢含量, 是测定过氧化氢含量的经典方法, 但存在着影响 因素多, 操作周期 , 分析费时费力的缺点此法根据不同浓度的过氧化氢水溶液同一温度下的 密度差别来分析过氧化氢水溶液中过氧化氢含量, 分析了其可靠性, 指出该方法具有准确简便 易掌握的优点 : 过氧化氢溶液; 浓度; 密度法; 称量法; 计算法 : O657 : A : 1001-4020(2002) 07-0339-03 DETERM INAT ION OF CONT ENTS OF H O IN ITS AQUEOUS SO UT ION 2 2 BY DENSITY METHOD YOU Qing- liang, RONG Jia-cheng, LI A-i kui, SHE Wan-neng ( Center of Op tical F iber Mater ials , H ube i R esearch I nstitute of Chem istry , W uhan , 430073, China) The density method was proposed for the determination of concentration of H O of its aqueous solu- Abstract 2 2 tion. T he density of the unknow n sample was firstly found by the weighing method as compared with the density of pure w ater at 25 . And then the concentration of H O in the aqueous sample solut ion (in mass percentage) w as calculatedby 2 2 t he extrapolation methodusing the known data obtained from the coversion table of concentrat ion of H O in aqueous solu- 2 2 tion to the corresponding density. For instance, the density ( ) of an unknow n H O solution was found to be 1. 1025g 2 2 ml- 1. As found from the conversion table, the density values 1. 0694gml- 1[for w (H O ) = 2