材料加工形态学52.聚合物加工结构性能静态混合器.ppt

混炼器加工的聚合物结构与性能 分散相尺寸的控制 特殊设备中的混合形态 Pan-Milling Miniature mixers MINI-MAX Molder 无机填料对形态的影响 加工的影响因素 Sheet Formation Pan-milling mixing Pan-milling mixing Melt Mixing of Polycarbonate with Multi-Walled Carbon Nanotubes Melt Mixing of Polycarbonate with Multi-WalledCarbon Nanotubes Improvement of a gram-scale mixer 混炼器加工的聚合物结构与性能 分散相尺寸的控制 特殊设备中的混合形态 无机填料对形态的影响 Nanoclay Carbon Nanotube 加工的影响因素 Nanoclay-Induced Morphology Development Nanoclay-Induced Morphology Development Organoclay Nanocomposites Morphology 混炼器加工的聚合物结构与性能 分散相尺寸的控制 特殊设备中的混合形态 无机填料对形态的影响 加工的影响因素 Time Ω……. Quiescent Annealing mixing conditions on the morphology and properties Coalescence and interfacial tension Quiescent Annealing Quiescent Annealing Quiescent Annealing Quiescent Annealing Quiescent Annealing Quiescent Annealing * * Sundararaj U , Dori Y, Macosko C W. Polymer, 1995, 36: 1957 the effect of viscosity ratio for changing PP viscosity effect of shear rate PP3050/ PS666D Morphology of: (a) PP/PA6 (80/20, w/w) blend; (b) PP/PA6 moulded from mixed PP/PA6 (80/20, w/w) powder pan-milled for 20 cycles. FTIR spectra of: (a) PP; (b) PP extracted from PP/PA6 (80/20,w/w) compound powder pan-milled for 10 cycles; (c) PP/PA6 (80/20, w/w)compound powder pan-milled for 20 cycles Zhe Chen, Q. W. (2001). Pan-milling mixing - a novel approach to forming polymer blends and controlling their morphology. Polymer International 50(9): 966-972. Zhe Chen, Q. W. (2001). Pan-milling mixing - a novel approach to forming polymer blends and controlling their morphology. Polymer International 50(9): 966-972. TEM micrographs of PC/MWNT prepared from APAM(a, d, g, j), MBM(b, e, h, k) and DACA(c, f, i, l). MWNT content is 0.50 wt.-%in (a), (b) and (c); 0.75 wt.-%in (d), (e) and (f); 1.00 wt.-% in (g), (h) and (i); and 1.25 wt.-% in (j), (k) and (l). Bin Lin, U. S. P. P. (2006). Melt Mixing of Polycarbonate with Multi-Walled Carbon Nanotubes in Miniature Mixers. Macromolecular Materials and En