不同分散剂对纳米铋粉在无水乙醇中分散性能影响.pdfVIP

St udy on Pract ical Technique 杨江海, 张振忠,赵芳霞,曹 娟, 江成军 ( , 210009) : 在用直流电弧等离子体法制备纳米铋粉的基础上, 通过研究pH 值对纳米铋粉分散性能 响,选用不同分散剂,研究了 不同超声时间和不同分散剂加入量条件下,聚乙烯吡咯烷酮( PVP) 聚乙二醇4 000( PEG) 油酸( OA) 三种分散剂对纳米铋粉 在无水乙醇中分散性能的 响结果表明, 加入聚乙烯吡咯烷酮及聚乙二醇分散剂的分散效果随着超声时间和表面活性剂 加入量的增加呈现先增大后减小的趋势, 而加入油酸的溶液分散性出现了波动;聚乙烯吡咯烷酮和聚乙二醇对纳米铋粉的分 散性较好; 不同分散剂分散效果从高到低顺序依次为: 聚乙烯吡咯烷酮 聚乙二醇 油酸最佳分散工艺为: 聚乙烯吡咯烷 酮加入量5%,超声功率 560 W,超声时间50 in : 纳米铋粉;直流电弧蒸发; 分散;表面活性剂 + 7 :TG146. 1 :A : 1000- 8365(2008) 12-1708-04 Effect of Different Surfactants on the Dispersion Propert ies of Bismuth Nanopart icles in the Alcohol Solvent YANG Jiang-hai, ZHANG Zhen-zhong, ZHAO Fang-xia, CAO Juan, JING Cheng- un ( College of Materials Science Engineering, Nan ing University of Technology, Nan ing 210009, China) Abstract: On t he basis of measuring dispersion propert ies of bismuth nanopart icles which was prepared by DC Arc plasma evaporat ion in different pH value alcohol solvent , t hree different dispersants were selected in this investigat ion The influences of supersonic dispersing t ime and surfactant concentrat ion on t he dispersion propert ies of t he bismuth nanoparticles in the alcohol solvent were systematically studied, in which PVP, Oleic acid, Poly et hylene glycol were employed as surfactants The results show that, with t he increase in ultrasonic dispersing time and t he concentrat ion of PVP and Poly et hylene glycol, the dispersion property of the suspension increases, and then decreases However, the addition of oleic acid results in a fluct uat ion of dispersion property The effect of three surfactants on the dispersion property of the suspension has a descending order as follows: PVP Poly et hylene glycol Oleic acid The opt imum dispersion parameters are that the addition of PVP, ult rasoni