两步法合成高质量Silicalite-1分子筛膜.pdfVIP

两步法合成高质量Silicalite-1 分子筛膜1 1,2 2 2 1 管卉 郑均林 孔德金 黄民 1.同济大学化学系，上海 200092 ； 2.中国石油化工股份有限公司上海石油化工研究院，上海 201208 摘要：使用一种新颖的两步合成方法，在多孔氧化铝陶瓷管（孔径0.1-0.5 µm ）表面，制备 了致密的Silicalite-1 分子筛膜。生成分子筛膜前，先采用 sol-gel 法在氧化铝管表面浸渍生 长一层二氧化硅缓冲层，SEM 表征表明，得到平整连续的缓冲层膜，达到了修饰载体材料 表面性能的目的。先用改性剂溶液对镀有缓冲层的α-Al2O3 陶瓷管进行浸泡处理，再采用水 热法在Silicalite-1 合成体系中生长分子筛膜，利用该两步合成方法制备出高质量Silicalite-1 分子筛膜，并考察了一定晶化条件对生长分子筛膜的影响。由于Silicalite-1 分子筛膜具有适 宜的孔道结构和孔径尺寸，可以在分子水平上实现多种难分离混合物的筛分，还可用于反应 -分离一体化工艺的开发，在对二甲苯生产领域具有广阔的应用前景。 关键词：沸石膜；Silicalite-1；水热合成；分离 Synthesis of high quality Silicalite-1 membrane by a novel two-step method GUAN Hui1,2 ZHENG Junlin2 Kong Dejin2 2 1 XIE Zaiku HUANG Min 1.Dpartment of chemistry, Tongji University, Shanghai 200092, China; 2.Shanghai Research Institute of Petrochemical Technology, Sinopec , Shanghai, 201208, China Abstract: Compact Silicalite-1 membranes were successfully synthesized on the alumina porous supports (pore size of 0.1-0.5 µm) through a novel two-step synthesis method. Mesoporous silica layers was coated on the surface of the support by sol-gel technique before zeolite membrane was 通讯作者：孔德金 通讯地址：上海市浦东新区浦东北路1658 号 201208 电话：021 E-mail: djkong@ prepared. SEM images showed that continuous buffer layer membrane covered the inner surface of the alumina tubes. Then high-quality Silicalite-1 membranes were achieved by the two-step synthesis method. In the first step, alumina ceramic tubes with buffer layer were immersed in modifier solution for a few hours. The second step was to prepare Silicalite-1 membrane through hydrothermal synthesis. Effects of crystallization temperature and crystallization time