湿化学法制备LTSOFCs材料及其性能研究.pdfVIP

湿化学法制备LT—SOFCs材料及其性能研究 丁 姣．尹国强。龚 圣．刘其海．郭清兵 (仲恺农业I：程学院化学化丁=学院．广东广州5】0225) 成的粉体成功制备了GDC膜电解质阳极支撑型固体氧化物燃料电池。并对单电池的电化学性能和稳定性进行了分析和 研究。单电池在加湿氨气(3％H20)燃料中，600℃下最大输出功率密度达384mW／crn2，并在550oC下经历了约12h的 稳定性测试。输出电压恒定．电池稳定性良好。 关键词：固体氧化物燃料电池；湿化学法；电池材料：性能 中图分类号：TM911 文献标识码：A 文章编号：1002—087 X(2012)07—0991埘 and ofLT-SOFCswithmaterials Preparationperformance synthesized wet—chemicalmethod by DING Jiao，YIN Guo-qiang．GONGSheng，LIUQi—hai。GUOQing—bing andChemical and (CollegeofChemistry Engineering,ZhongkaiUniversityofAgriculture Engineering, rdusngzhour．3uangdong510225,China) Abstract：NiOanode rnatedaland matedal，LSCF(Lao§ro正a出0803)cathode for solidoxiderueI wet-chemicaImethod．TheXRD powderIow-temporatumcells(LT—SOFCs)wereby synthesized showlhat of threekinds the structurewithout patterns as-preparedpowderspresentexpected impurityphases．The GDC membranesolidoxidefueIcellswere fabricated．Theelectrochemical anode-supportedelectrolyte successfully and of cellweretestedand pedormancestabilitysingle moist asfuel，thecell investigated．Withhydrogen single exhibitsthemaximum of384mW／cm2at600℃and the teslof12hours．The powerdensity ex