LiFePO4Ni复合微球的制备.pdfVIP

第36卷第4期 硅酸盐学报 V01．36，No．4 THE 2008年4月 J()I壤NAI，OFa田时ESECERAMCSoa口巳1_Y April，2008 LiFePOa／Ni复合微球的制备 韩辩，沈湘黔，周建新 (菠苏大学砉|料科学与工程学院，江苏镟江212013) 擞壤耱辩，劳采矮热善§差热分辑、织搓毫子显檄辘、能谱分掇、x越线戆瓣等手段硬究≯熬驱薅亵媾烧声赞耱残努、皴鼹结构、澎貔及箕燕分瓣避 表面． 关建蔼；辩酸铁彰镰复合镦簿；禳翻友瘟滚$和戆辘法；耪檬羧薤凝薮法 中圈分粪号：TM912．9文献标识码：A 文章编号；0454--5648(2008)04-0559--06 PREPARATIONOF COMPOSITEMICROSPHERES LiFeP04／Ni HAN Cong，SHENXiangqian，ZHOUJianxin ofMaterialsScienceand (School Engineering．Jiangsu 212013，Bangsu,China) University,Zhenjiang were controllable reaction then Abstract：LiFeP04mierospheresfirstlysynthesizedby precipRation-calcinationmethod，and were Ni-citrateon followedthermalre- LiFePOJNicompositemicrospherespreparedbycoating gelsLiFeP04microspheresby duction．The and ofthe resultant werecharacterized morphologypfe㈤O鹤and composition,structure compositepowders by electron and elemental ther- X-raydiffraction，scanningmicroscopyenergydispersivespectroscopy real ofthe studiedvia thermal decompositionprocessesprecufso塔werethermogravimetric-differentialanalysis．Theexperi- results mental demonstratesthatthe consistsof andNi as-preparedLiFeP04／Nicompositemicrospheres LiFeP04crystal- only metal line a