Nd含量对快淬纳米晶和非晶（Mg24Ni10Cu2）100-xNdx（x=0~20）合金电化学性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 3668−3676 Effect of Nd content on electrochemical performances of nanocrystalline and amorphous (Mg Ni Cu ) Nd (x=0−20) alloys prepared by melt spinning 24 10 2 100−x x 1,2 2 1,2 1 1 2 Yang-huan ZHANG , Tai YANG , Wen-gang BU , Ying CAI , Guo-fang ZHANG , Dong-liang ZHAO 1. Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China; 2. Department of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081, China Received 12 September 2013; accepted 21 October 2013 Abstract: The nanocrystalline and amorphous Mg Ni-type alloys with a chemical composition of (Mg Ni Cu ) Nd (x=0, 5, 10, 2 24 10 2 100−x x 15, 20) were fabricated by melt spinning technology. The effects of spinning rate on the structure and electrochemical hydrogen storage performance of the alloys were investigated. The as-spun Nd-free alloy displays an entire nanocrystalline structure, whereas the as-spun Nd-added alloys hold a nanocrystalline and amorphous structure, suggesting that the addition of Nd facilitates the glass forming of the Mg2Ni-type alloys. Increasing the spinning rate from 0 to 40 m/s gives rise to the discharge capacity growing from 42.5 to 100.6 mA·h/g for the x=0 alloy and from 86.4 to 452.8 mA·h/g for the x=10 alloy. And th