PtCeO2-ZrO2-La2O3柴油车尾气氧化催化剂活性及抗硫性能.pdfVIP

0253-9837(2011)09-1469-08 10.1016/S1872-2067(10)60259-8 Pt/CeO2-ZrO2-La2O3柴油车尾气氧化催化剂活性及抗硫性能 钟富兰 钟喻娇 肖益鸿，蔡国辉， 郑 勇 魏可镁* 福州大学化肥催化剂国家工程研究中心，福建 福州 350002 摘要：采用两种方法制备了三种Pt/CeO2-ZrO2-La2O3柴油车尾气氧化催化剂，并用X射线衍射、N2物理吸附、程序升温还原、 程序升温脱附、X射线荧光光谱和红外光谱等方法对其进行了表征.结果发现，制备方法对催化剂的结构、织构、抗硫性能及 催化性能的影响非常大.对其进行硫中毒，导致起燃温度明显升高.将ZrO2和La2O3沉积在CeO2表面所制得的 Pt/CeO2-ZrO2-La2O3催化剂表现出更高的抗硫及催化氧化性能，这主要归功于Pt在富Zr载体表面具有更高的分散性. 氧化铈;氧化锆;氧化镧;铂；沉积沉淀；硫中毒；柴油车尾气净化 O643 A 2011-04-18 2011-06-03 国家科技支撑计划(2007BAE08B01). SulfurResistanceandActivityofPt/CeO2-ZrO2-La2O3 DieselOxidationCatalysts ZHONGFulanZHONGYujiaoXIAOYihongCAIGuohuiZHENGYongWEIKemei NationalEngineeringResearchCenterofChemicalFertilizerCatalyst,FuzhouUniversity,Fuzhou350002,Fujian,China Abstract:ThreePt/CeO2-ZrO2-La2O3dieseloxidationcatalystswerepreparedbytwodifferentroutesandcharacterizedbyX-raydiffraction, N2adsorption,temperature-programmedreduction,temperature-programmeddesorption,X-rayphotoelectronspectroscopy,andinfrared spectroscopy.Thesynthesisprocedureaffectedthestructure,texture,sulfurresistance,andcatalyticactivityofthecatalysts.Sulfurpoisoning increasedthelight-offtemperatureofallthecatalysts,butthePt/CeO2-ZrO2-La2O3catalystpreparedbydepositingZrO2andLa2O3onthe surfaceofCeO2nanoparticlesexhibitedbettersulfurtoleranceandcatalyticactivitywithsimulateddieselemissionduetothehighdispersion ofPtonCeO2-ZrO2-La2O3oxidewithaZr-riehsurface. ceria;zirconia;lanthana;platinum;deposition-precipitation;sulfur-poisoning;dieselexhaustpurification 2011-04-18 2011-06-03 ThisworkwassupportedbytheNationalKeyTechnologyRDProgram(2007BAE08B01). 万方数据 Experimental 万方数据 Activitytest 万方数据 1472 万方数据