110_2_游离氰的测量.pdfVIP

No. 110/2 e Application Bulletin Of interest to: General analytical laboratories B 1, 2 Water, waste water, environmental protection Polarographic determination of free cyanide Summary This Bulletin describes a polarographic method for the determination of cyanide that allows to determine free cyanide fast and accurately. The determination also suc- ceeds in solutions containing sulfides, where other methods fail. Cyanide concen- trations in the range ß(CN– ) = 0.01...10 mg/L cause no problems. Interference caused by anions and complexed cyanides has been investigated. Instruments and accessories • 746 VA Trace Analyzer with 747 VA Stand or • 757 VA Computrace Reagents All reagents used should have the highest possible degree of purity (p.a. or su- prapur). Only ultrapure water should be used. • Potassium hydroxide KOH, puriss. p.a., purity ≥86%, CAS 1310-58-3 • Boric acid H BO , puriss. p.a., CAS 10043-35-3 3 3 • Potassium cyanide KCN, puriss. p.a., CAS 151-50-8 Ready-to-use solutions • Supporting electrolyte: c(H BO ) = 0.2 mol/L, c(KOH) = 0.17 mol/L, pH 10.2: 3 3 Dissolve 11.2 g KOH in approx. 800 mL ultrapure water. Add 12.4 g boric acid, adjust the pH value to 10.2 if necessary and make up to 1 L with ultrapure water. • Potassium hydroxide solution, c(KOH) = 0.01 mol/L: Dissolve 0.65 g KOH