碳化硅陶瓷的纳米强化增强机理.pdfVIP

中国空间科学学会空间材料专业委员会2009学术交流会 碳化硅陶瓷的纳米强化增强机理 郭兴忠朱潇怡张玲洁李海淼杨辉 (浙江大学材料科学与工程学系，浙江杭州310027) 摘要：以水摹喷雾造粒制备的纳米碳化硅复合粉体造粒粉为原料，采用无压烧结制备纳米复合碳化硅 陶瓷，探讨r纳米颗粒强化增韧碳化硅陶瓷的机制。研究结果表明，与未加纳米颗粒相比，加入纳米 颗粒后碳化硅陶瓷的力学性能明显提高，其抗弯强度、硬度和断裂韧性分别达到557MPa、21GPa和 6．6MPa·m“2。纳米颗粒强化增韧碳化硅陶瓷的机制有钉扎、晶界强化、裂纹偏转以及裂纹桥联。 关键词： 碳化硅陶瓷：性能；显微结构；强化增韧 中图分类号：064 MechanismofSiliconCarbideCeramicReinforced and ToughenedbyNanoparticles GUO ZHU ZHANG LI HaimiaoYANGHui XingzhongXiaoyi Lingjie ofMaterialsScienceand 1 (Department Engineering，ZhejiangUniversity,Hangzhou,30027，E＆China) Abstract：WithSiC as granulatedpowdefcontainingnanoparticlesbyspraydryingtechniquestartingmaterials’ and ceramicswere by and nanocompositepreparedpressurelesssinteringtechnology．11hereinforcingtoughening mechanism for carbideceramicwere of silicon withthoseofsiliconcarbide nanoparticles discussed．Compared ceramicwithout siliconcarbideceramics had mechanical nanoparticlcs，the containingnanoparticleshigh withthe of hardnessof2lGPaandfracture of properties bendingstrength557MPa,Vickers tough[1eSS crack were deflectionand 6．6MPa’m“‘respectively．Nanoparticle-pining，boundarystrengthening，crack bridging themainmechanismfor carbidereinforcedand silicon tough∞ed bynanoparticles． Siliconcarbide and Keywords： ceramics；Properties；Microstructure；Reinfo