低浓度甲烷流向变换催化燃烧.pdfVIP

第40卷 第11期 北 京 工 业 大 学 学 报 Vol.40 No.11 2014年 11月 JOURNAL OF BEIJING UNIVERSITY OFTECHNOLOGY Nov. 2014 低浓度甲烷流向变换催化燃烧 梁文俊,刘 欢,李 坚,王洪明,李玉泽,何 洪 (北京工业大学 区域大气复合污染防治北京市重点实验室,北京 100124) 摘 要:以水铝石和改性过的酌-Al O 为原料制备了铝溶胶涂层,考察了不同涂层固含量对催化剂比表面积的影 2 3 响. 以贵金属Pd作为催化剂活性成分,研究了催化剂在不同Pd含量和还原条件下催化活性的变化规律,并考查了 催化剂预热温度、系统换向周期对反应系统床层温度的影响. 结果表明:涂层固含量20%、Pd负载量占涂覆层质量 -1 分数1.5%为催化剂最佳制备条件;当催化剂预热温度为450益、空速为15000h 、换向周期为10min、甲烷体积分 数为0.2%时,甲烷转化率最高可达85%. 关键词:整体式催化剂;低浓度甲烷;催化燃烧;流向变换 中图分类号:TE992.1 文献标志码:A 文章编号:0254-0037(2014)11-1730-05 Catalytic Combustion of Lean Methane in a Reverse-flow Reactor LIANG Wen-jun,LIU Huan,LI Jian,WANG Hong-ming,LI Yu-ze,HE Hong (Beijing University of Technology,Key Laboratory of Beijing on Regional Air Pollution Control,Beijing 100124,China) Abstract:The washcoat deposited on a ceramic honeycomb was prepared with modified 酌-Al O and 2 3 pseudo boehmite. The effect of gel solid content on the gel viscosity and coating ability wasinvestigated. The monolithic catalystswere made with noble metal being active component,cordierite and modified 酌- Al O being the first and second carriers. The effects of Pd content and deoxidation on the monolith 2 3 catalyst performance, the effects of the cyclic period, and preheated temperature on the operation performance of reactor were investigated. Result show that the quantity supported Pd of coating layer being 1.5% and the coating of solid content being20% was the best. The methane conversion attained