Au3Cu亚格子系统的合金基因Gibbs能配分函数和平衡全息网络相图（英文版）.pdfVIP

Trans. Nonferrous Met. Soc. China 25(2015) 211−240 Alloy gene Gibbs energy partition function and equilibrium holographic network phase diagrams of Au3Cu-type sublattice system 1,2,3 4 5 6 1,2,3 Youq-qing XIE , Yao-zhuang NIE , Xiao-bo LI , Hong-jian PENG , Xin-bi LIU 1. School of Materials Science and Engineering, Central South University, Changsha 410083, China; 2. Powder Metallurgy Research Institute, Central South University, Changsha 410083, China; 3. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China; 4. School of Physics and Electronics, Central South University, Changsha 410083, China; 5. School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China; 6. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China Received 17 November 2014; accepted 8 January 2015 Abstract: Taking Au Cu-type sublattice system as an example, three discoveries have been presented. First, the fourth barrier to 3 hinder the progress of metal materials science is that today’s researchers do not understand that the Gibbs energy function of an alloy phase should be derived from Gibbs energy partition function constructed of alloy gene sequence and their Gibbs energy sequence. Second, the six rules for establishing alloy gene Gibbs energy partition function have been discovered, and it has been specially proved that the probabilities of structure units occupied at the Gibbs ene