GTL过程中轻烃回收的膜分离耦合工艺.pdfVIP

GTL过程中轻烃回收的膜分离耦合工艺 * 柴永峰，贺高红 ，石文华，阮雪华，朱莹 (大连理工大学精细化工国家重点实验室，膜科学与技术研究开发中心，大连 116012) 摘要：为提高GTL 合成驰放气的利用率，低能耗低成本地回收轻烃资源，提出膜分离和传统分离技 术耦合的新过程；以 133,000Nm3/h 的驰放气为原料，采用HYSYS 流程模拟软件对新工艺进行模拟 优化，确定了最优的操作参数。可以得到LPG和轻油的产量、浓度以及回收率分别为5.533t/h，3.442t/h、 99.1mol%，99.9mol%和 77.4%和 81.3%。每年回收的H2 和轻烃资源可创造 4.8 亿元的经济效益。 关键词：GTL；费托合成；驰放气；轻烃；膜分离；HYSYS 模拟 Recovery of Light Hydrocarbon from GTL process by Integration of Membrane Technology * CHAI Yongfeng, HE Gaohong , SHI Wenhua, RUAN Xuehua, ZHU Ying (State Key Laboratory of Fine Chemicals, R D Center of Membrane Science and Technology, Dalian University of Technology, Dalian 116012 ) Abstract: For the sake of improving utilization of GTL vent gas and recovering light hydrocarbon from vent gas with low cost, a new coupling process of membrane system and traditional technology has been 3 proposed. The process was simulated and optimized by HYSYS software to process 133,000Nm /h vent gas. The optimal operation parameters were determined. With the help of HYSYS computation, the output of LPG and light oil is 5.533t/h and 3.442t/h. Concentration and recovery reach 99.1mol%, 99.9mol% and 77.4%, 81.3% respectively. Through cost analysis, the annual economic benefit can be as high as 4.8 hundred million Yuan. Keywords: GTL; F-T synthesis; vent gas; light hydrocarbon; membrane separation; HYSYS simulation GTL （Gas to Liquids ）是始于 1923 年发明 途径[1,2] 。随着石油价格的不断上涨，人们对绿 的费托工艺的一种由天然气经合成气制取液体 色能源的关注越来越高，GTL 以其产品十六烷 值高以及不含硫、芳烃等优点成为世界各国开 基金资助：新世纪优秀人才支持计划资助（NCET-06-0272 ） 第一作者简介：柴永峰（1983-），男，内蒙古鄂尔多 发研究的热点[3,4] ，但在费托合成驰放气处理 斯市人，硕士研究生，主要从