氢键诱导的聚吡咯苯磺酸功能化多壁碳纳米管的制备及其电化学行为.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) November A cta Phys. Chim. Sin., 2009, 25(11) ：2199-2204 2199 [Article] 氢键诱导的聚吡咯/苯磺酸功能化多壁碳纳米管的制备及其电化学行为 清宾 高 博 苏凌浩 原长洲 卢向军 张校刚* ( 京航空航天大学材料科学与技术学院, 南京 210016) 摘要： 采用原位芳基重氮化反应对碳纳米管进行苯磺酸功能化, 进而制备了聚吡咯/苯磺酸化碳纳米管复合材 料(PPy/f MWCNTs), 通过透射电镜(TEM)及扫描电镜(SEM)测试发现, 氢键诱导使聚吡咯成功地包覆在碳纳米 管表面. 循环伏安和恒流充放电测试结果表明, 复合材料具有良好的电化学电容性能, 当聚吡咯与苯磺酸化碳纳 米管质量比为1颐1 , 复合材料在1.0 A ·g-1 的电流密度下的比容量达266 F ·g-1, 而且聚吡咯利用率比未功能化 聚吡咯/碳纳米管(PPy/p MWCNTs)和纯聚吡咯(PPy)提高了1 倍以上. 关键词： 超级电容器; 聚吡咯; 碳纳米管; 苯磺酸功能化 中图分类号： O644; TB383 Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior FU Qing Bin GAO Bo SU Ling Hao YUAN Chang Zhou LU Xiang Jun ZHANG Xiao Gang* (College of Material Science and Engineering, Nanji ng University of A eronautics and Astronautics, Nanj ing 210016, P. R. China) Abstract ： Multi walled carbon nanotubes were functionalized using in situ generated aryl diazonium and were then used to synthesize polypyrrole/benzenesulfonic functionalized multi walled carbon nanotube composites (PPy/f MWCNTs). Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) results indicated that a uniform PPy was successfully coated onto the sidewall of the f MWCNTs, which was induced by hydrogen bonding. Cyclic voltammetry and galvanostatic charge/discharge measurements results showed that the composite possessed good electrochemical capacitive performance. The compo