水蒸气对褐煤原位气化半焦反应性能及微观结构的影响.pdfVIP

第43卷 第5期 燃摇 料摇 化摇 学摇 学摇 报 Vol.43 No.5 2015年5月 Journal of Fuel Chemistry and Technology May2015 文章编号:0253鄄2409(2015)05鄄0546鄄08 水蒸气对褐煤原位气化半焦反应性能及微观结构的影响 许修强,王永刚,陈国鹏,陈宗定,秦中宇,戴谨泽,张摇 书,许德平 (中国矿业大学(北京) 化学与环境工程学院,北京摇 100083) 摘摇 要:为了揭示水蒸气对半焦反应性和微观结构的影响,在自制两段新型反应器上依次进行了褐煤干燥、热解及“热冶焦的 水蒸气原位气化研究。 利用TGA、BET和Raman光谱仪,对原位气化半焦进行反应性和微观结构解析。 结果表明,在反应温 度为600 益时,水蒸气对半焦转化率、反应性及微观结构影响很小。 温度达到700 ~900 益,在半焦与水蒸气接触的前2min, 虽然半焦转化率变化不大,但其反应性、小环(3 ~5 个芳环)与大环(逸6 个环)体系之比及含氧官能团却急剧降低;大于 2min,半焦转化率逐渐增大,反应性、小环与大环之比及含氧官能团缓慢降低;而半焦孔结构在2min 前后却具有基本一致的 变化趋势。 半焦与水蒸气接触的前2min,小环与大环之比和含氧官能团急剧降低是导致反应性显著降低的重要因素,大于 2min,芳环体系的变化是导致反应性进一步降低的原因。 关键词:褐煤;半焦;水蒸气;原位气化;反应性;微观结构 中图分类号:TQ546摇 摇 文献标识码:A Effects of steam on the reactivity and microstructure of char from in鄄situ gasification of brown coal XU Xiu鄄qiang,WANG Yong鄄gang,CHEN Guo鄄peng, CHEN Zong鄄ding,QIN Zhong鄄yu,DAI Jin鄄ze,ZHANG Shu,XU De鄄ping (School of Chemical and EnvironmentalEngineering, China University of Mining and Technology (Beijing),Beijing摇 100083,China) Abstract:To examine the effects of steam on the char reactivity and its microstructure,experiments of drying and pyrolysis of brown coalaswellasthein鄄situ gasification of hot char werecarriedoutinanewly鄄designed two鄄stage reactor. Thereactivityandmicrostructure ofin鄄situ gasification char werecharacterizedbyTGA,BET and Raman spectroscopy respectively. The results show that at low temperature of 600 益,the steam has little effect on the conversion,reactivity andmicrostructure of char. When itreaches700~900益,thereare different change trendsbefore and after 2min of reaction between char and steam. In the first 2min,the reactivity,the ratio of small aromatic ring systems (3 ~5 rings) to the large fused rings (逸6 r