硫酸高铈催化合成乙酸丙酯.pdfVIP

2015年2月 工业催化 Feb.2015 第23卷 第2期 INDUSTRIAL CATALYSIS Vol.23 No.2 精细化工与催化 硫酸高铈催化合成乙酸丙酯 1* 2 訾俊峰 ，宋少堂 （1.许昌学院化学化工学院，河南许昌461000；2.河南省农科院烟草研究所，河南许昌461000） 摘 要：以硫酸高铈为催化剂，冰乙酸和正丙醇为原料，环己烷为带水剂合成乙酸丙酯，研究正丙醇 与冰乙酸物质的量比、反应时间、催化剂用量及重复使用次数对酯化率的影响。经正交实验及单因 素实验得到反应的最佳合成条件为：冰乙酸用量0.1 ol，醇酸物质的量比1.5，硫酸高铈用量1.1g， 反应时间2.0 h，此条件下，酯化率约为99％。该催化剂具有催化活性高、操作简单和不污染环境 等优点。 关键词：精细化学工程；硫酸高铈；冰乙酸；正丙醇；乙酸丙酯 doi：10.3969/ j.issn.1008-1143.2015.02.016 ＋ 中图分类号：O623.624 1；O643.36 文献标识码：A 文章编号：1008-1143（2015）02-0156-03 Synthesis of propyl acetate catalyzed by ceric sulfate 1* 2 ZiJunfeng ，Song Saotang （1.School of Che istry and Che ical Engineering，Xuchang University，Xuchang461000，Henan，China； 2.Tabacco Research Institute，Henan Acade y of Agricultural Sciences，Xuchang461000，Henan，China） Abstract：Using ceric sulfate asthe catalyst，glacial acetic acid andn-propyl alcohol asraw aterialsand cyclohexane as water carrying agent，propyl acetate was synthesized by esterification reaction. The influence of olar ratio of n-propyl alcohol to glacial acetic acid，reaction ti e，ceric sulfate dosage and repeated use ti es on the esterification rate was investigated.The opti al condition of the esterification reaction was deter ined by orthogonal tests and single factor experi ents.The results showed that the esterification rate of about 99％ was attained under the opti al condition as follows：glacial acetic acid a ount0.1 ol，olar ratio of n-propyl alcohol to glacial acetic acid 1.5，ceric sulfate dosage 1.1g and reaction ti e2.0 h.The catalyst had the feat