Photochemistry：ScrambledbytheSun.pdf

news views efficiency of convergent synthesis — but functionalities were already present in the First, with a synthetic route available, the varied and unique stereochemical structure. The key was finding a way to stitch analogues can now be prepared to arrangements point to no specific order it together into the final framework with the determine what structural features are of installation. What is certain, however, correct three-dimensional shape. A Diels– key for their biological activity, as well as 7 is that whichever of these stereocentres Alder reaction induced by Me AlCl did the what alterations can potentially enhance 2 are present, they are likely to influence the majority of the work in a single step, with their desirable properties. Second, there course of future reactions in both desired, the final stereochemistry of 7 governed by is far more to learn about the underlying as well as potentially undesired, directions. the lone stereocentre next to the furan ring biochemistry of how this molecule acts, Despite these obstacles, the researchers were system in the starting material. From here, given that some preliminary screens able to develop a highly creative strategy, some fluctuations in oxidation state and of synthetic solanoeclepin A (2) could one empowered largely through known