重金属在煤气化过程的分布迁移规律及控制.pdfVIP

中国环境科学 2002,22(6)：556~560 China Environmental Science 重金属在煤气化过程的分布迁移规律及控制 * 王云鹤,李海滨,黄海涛,陈 勇 ( 中国科学院广州能源研究所,广东 广州 510070) 摘要：选用2 种气化用煤——大同煤和神府煤,进行水蒸气气化实验,研究了在不同温度下重金属元素——砷(As)、镉(Cd)、铬(Cr)、汞(Hg) 和铅(Pb)在气化产物中的分布.实验数据表明,重金属元素主要富集在气化灰中或是散发到大气中,同时,在焦油中重金属元素也有一定的含 量,尤其是Cd,在焦油中的含量达到总量的22%~37%.添加无水CaSO ,高岭土,铝土矿,无水CaCO 4 种不同的吸附剂,发现不同的吸附剂对 4 3 不同的重金属有不同的吸附作用.4 种吸附剂对重金属元素的吸附既有物理吸附,又有吸附剂与重金属之间的化学反应. 关键词：煤；重金属；气化；吸附剂 中图分类号：X701.3 文献标识码：A 文章编号：1000-6923(2002)06-0556-05 Distribution rule and control of heavy metals during coal gasification. WANG Yun-he, LI Hai-bin , HUANG Hai-tao , CHEN Yong (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences , Guangzhou 510070, China). China Environmental Science. 2002,22(6)：556~560 Abstract：Steam gasification test of two kinds of coal from Datong and Shenfu was made; and distribution of heavy metal elements (As, Cd, Cr, Hg and Pb) in the product from coal gasification under different temperature was studied. The test data indicated that heavy metal elements enriched mainly in gasification ash or emitted to atmosphere; at the same time, there was definite content of heavy metal elements in the gasification tar, especially Cd, of which the content reached 22%~37% of the total amount. Four different sorbents (CaSO , kaoline, CaCO and bauxite) were used to make the 4 3 control test of heavy metals; and different sorbents were found to have different adsorption of heavy metal. These sorbents not only had physical adsorption of heavy metals but also had chemical reaction between sorbents and heavy metals. Key words ：coal；heavy metal；gasification；sorbent 煤中除了含有C,H,N,O 等常量元素外,还含 1 实验部分 有很多痕量的重金属元素,如:As, Cd