木质素基偶氮聚合物胶体球地制备.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) March Acta Phys. -Chim. Sin. 2015, 31 (3), 505-511 505 [Article] doi: 10.3866/PKU.WHXB201501192 木质素基偶氮聚合物胶体球的制备 邓永红 刘友法 张伟健 邱学青* (华南理工大学化学与化工学院, 制浆造纸国家重点实验室, 广州510640) 摘要: 利用造纸废液中的碱木素(AL)合成了木质素基偶氮聚合物(AL-azo-COOEt), 并研究其自组装胶体化过 1 程. 木质素偶氮聚合物的成功合成通过核磁共振氢谱( H NMR)、紫外-可见(UV-Vis)光谱、傅里叶变换红外(FT- IR)光谱和元素分析等表征方法得到证实. 激光光散射(LLS)监测了AL-azo-COOEt 的胶体化过程, 自组装形成 的胶体球利用透射电镜(TEM)、扫描电镜(SEM)、X 射线光电子能谱仪(XPS)和元素分析等进行表征. 结果表明, 木质素偶氮聚合物通过疏水聚集作用可以形成规整的实心胶体球, 且为内部较疏水外部较亲水性质的结构. 木 质素偶氮聚合物胶体球可以包载疏水性药物阿霉素(DOX), 且其缓释性能可以通过缓冲溶液的pH 值来调控. 关键词: 碱木素; 偶氮聚合物; 自组装; 胶体球; 包载 中图分类号: O648 Formation of Colloidal Spheres from a Lignin-Based Azo Polymer DENG Yong-Hong LIU You-Fa ZHANG Wei-Jian QIU Xue-Qing* (State Key Laboratory of Pulp and Paper Engineering, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China) Abstract: 2-(4-Ethyl formate phenyl azo) phenol lignin-modified polymer (AL-azo-COOEt), a novel lignin- based azo polymer, has been successfully synthesized from alkali lignin (AL) recovered from pulping black liquor. The micellization process of the AL-azo-COOEt polymer was also studied. The synthetic products were characterized by elemental analysis, Fourier transform infrared (FT- IR) spectra, proton nuclear magnetic 1 resonance ( H NMR) spectroscopy, and ulraviolet-visible (UV