聚丙烯酸酯类偶氮聚电解质的静电逐层自组装及表面起伏光栅性能研究.pdfVIP

第4卷 第6期 2009 年 6 月 中国科技论文在线 Sciencepaper Online 391 聚丙烯酸酯类偶氮聚电解质的静电逐层自组装 及表面起伏光栅性能研究 和亚宁，王晓工 （清华大学化工系高分子研究所，北京100084） 摘 要：利用聚丙烯酸酯类偶氮聚电解质的DMF溶液以及DMF/H O溶液的静电逐层自组装，制备了偶氮聚电解质－ 2 + PDAC 自组装多层膜。研究了溶剂体系变化对自组装膜的影响。在干涉的P偏振 488 nm Ar 激光的作用下，在上述 2 种 溶剂体系中形成的偶氮聚电解质/PDAC 多层自组装膜均可在膜表面形成规则的正弦波形表面起伏光栅。光致表面起伏 光栅的形成能力与自组装采用的溶剂体系有关。 关键词：材料学；自组装；聚丙烯酸酯；偶氮聚电解质；表面起伏光栅 中图分类号：O631 文献标识码：A 文章编号：1673－7180(2009)06 －0391 －4 Self-assembly of a polyacrylate-based azo polyelectrolyte and its photoinduced surface relief gratings He Yaning ，Wang Xiaogong (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract: Self-assembled multilayer films of a polyacrylate-based azo polyelectrolyte were fabricated by an electrostatic layer-by-layer adsorption technique. By using dipping solutions of the azo polyelectrolyte in both anhydrous DMF and DMF/H + 2O mixed solvent, high quality multilayer films were obtained. With interfering illumination of Ar laser beams (488 nm), significant surface relief gratings formed on the self-assembled multiplayer films were observed. After the same irradiation time, the modulation depths of the two kinds of multilayers were different which can be attributed to the different structures of the multilayers. Key words: material science ；self-assembly ；polyacrylate-based ；azo polyelectrolyte ；surface relief gratings