氢气还原海绵铁去除水体中硝酸盐的研究.pdfVIP

第33卷第12期 I量砣尉鹳敢求 V01．33No．12 2010年12月 Environmental Dec．2010 ScienceTechnology 氢气还原海绵铁去除水体中硝酸盐的研究 李俊国‘， 王凡， 冯艳平， 李守章， 闫小林 河北理工大学冶金与能源学院，河北唐山063009 摘要：利用小球烧结和氢气还原工艺制备了粒径lmm～5mm的多孔性球形海绵铁，对球形海绵铁去除水体中硝酸盐的效率及去除动 力学进行了研究。结果表明：溶液初始pH值对硝酸盐去除效率的影响显著，初始pH值小于3时，硝酸盐的去除率随溶液初始pH的增加而 逐渐降低；初始pH值大于3时，硝酸盐的去除率又随之升高。硝酸盐浓度低于10mgN／L时，硝酸盐去除率随着硝酸盐初始浓度的增加而增 加，硝酸盐的残余量保持在0．4mgN／L左右；硝酸盐浓度高于20mgN／L时，硝酸盐的去除率随初始硝酸盐浓度的增加而略有降低。球形海绵铁 还原反应的进行，溶液pH值快速增加，氨氮以分子态氨的形式从水中逸出。进行归纳总结和对比，并以多环芳烃的提取为例列举了各方法的 应用步骤，从而为其他环境样品其他有机物分析预处理提供参考。 关键词：球形海绵铁；去除；硝酸盐；pH值；氨氮 中图分类号：X703．1文献标志码：A doi：10．3969／j．issn．1003—6504．2010．12．019 NitrateRemovalfromWater Iron bySphericalSpongePrepared Reduction H2 by LI Fan，FENG Xiao—lin Jun—guo+，WANG Yan—Ping，LIShou—zhang，YAN Schoolof and 063009，China MetallurgyEnergy，HebeiPolytechnicUniversity，Tangshan Abstract：Porous ironwithlmm～Smmdiameterwas with bymini—pelletsinteringintegratedH2 sphericalsponge prepared directreduction．Staticstate wasdoneto nitrateremoval from water experiment investigate efficiencypollutedbyspherical ironandtO nitratereductionreactionkinetics．Resultsindicatedthatinitial solutionhad sponge explore pH．in significant influenceonnitrateremovalrate．Nitrateremovalratedecreasedwith ofinitialwhenvaluewasbelow increasing pH pH 3， nitrateconcentration whileincreasedwhenvaluewasabove3．Nitrateremovalrateincreasedwith ofinitial pH increasing whenitwasbelow concentrationofnitrateresiduesabout initialnitrateconcentrationwas 10mg-N／L．with 0．4mg—N／L．When reduction than removalratedecreasedwith ofnitrateconcentration．Nitrate higher20mg-N／L，nitrate slightlyincreasing by order and reactionrate iron tobethefirstorderreaction．withthereaction0．970-1．378 sphericalspongeappeared apparent ammoniacould from constant ofnitratereductionwasammonium．Molecule—state 0．314h4—0．536h～．Majorproduct escape watersolutionbecausevalueincreasedwiththereductionreaction pH along carryingthrough． Keywords：sphericalspongeiron；removal；nitrate；pHvalue；ammonium 水中硝酸盐自身毒性较小，但在微生物作用下可 件下才能去