碳化对混凝土中氯离子扩散的影响_金祖权.pdf

30 8 Vol. 30 No. 8 2008 8 ournal of University of Science and Technology Beijing Aug. 2008 1) 2) 1) 金祖权 孙 伟 李秋义 1) , 266033 2) , 210096 0, 14, 28 d 35% NaCl 650 d, , ; , DSC . : , , , ; , . , 30 nm 11% , 17 nm; Friedel S , . ; ; ; ; T U 52801 Effect of carbonation on chloride diffusion in concrete JI N Zuquan1) , S UN Wei2) , LI Qiuyi1) 1) C llege f Civil and Engineering, Qingda T echn l gical University, Qingda 266033, Ch ina 2) C llege f Materials Science and Engineering, S uth east University, Nanjing 210096, China ABSTRACT C ncrete and paste w ere immersed in a 35% NaCl s lut i n f r 650d after they were quickly carb nated f r 0, 14 and 28 d. The free and t tal chl ride c ntents in different depths f c ncrete were tested t calculate the chl ride apparent diffusi n c effi- cient and the chl ride binding capacity. The p re structure and c rr si n pr ducti n f paste attacked by different c rr si n regimes w ere analyzed by mercury intrusi n p r simeter ( MIP) and differential thermal analysis ( DSC) , respectively. The results indicate t hat the chl ride c ntent and t he chl ride apparent diffusi n c efficient increase after quick carb nati n, h w ever the chl ride binding capacity f c ncrete reduce simultane usly; and the carb nati n influence increase w ith time. Quick carb nati n f c ncrete c arsens its p re structure that the capillary p re ( 30nm) am unt f paste increases by 11% and the m st pr bable p re size increases by 17 nm, but it decreases the FriedelS am unt in c ncrete and reduces the chemical chl ride binding capacity f c ncrete. KEY WORDS c ncrete; carb nati n; chl ride; apparent diffusi n c efficient ; p re structure . ,