磷钼蓝法测定水中有机磷农药残留方法改进.pdfVIP

农业环境科学学报 2007,26(5):1843-1848 JournalofAgro-EnvironmentScience 磷钼蓝法测定水中有机磷农药残留方法改进 1 2 刘 辉 ,陈国松 ( 徐州工程学院食品学院,江苏 徐州 ; 南京工业大学,江苏 南京 ) 1. 2210082. 210009 摘 要:采用纳米二氧化钛 光催化法预处理有机磷残留农药样品,用磷钼蓝分光光度法测定含量,并与国标法比较,确定了最佳 - 实验条件。选取了24种含磷农药光催化降解后,测定其中磷的含量。结果表明,相对于标准方法,总磷测出率达到95%以上,标准 偏差 为 -3,检出限为 -3。通过紫外扫描分析进一步验证了该方法可达到与国标法同样的降解效果。且比现行国标 SD 2.86×10 2.10×10 方法更易于实现仪器化,为设计和研制环境水样中总磷的在线监测仪器作了方法上的准备。 关键词:有机磷农药;光催化;纳米TiO;分光光度法;总磷;预处理 2 中图分类号: 文献标识码: 文章编号: X830.2 A 1672-2043(2007)05-1843-06 ImprovementonSpectrophotometryMethodforDeterminingOrganophosphorusPesticideResiduesinWater 1 2 LIUHui,CHENGuo-song (1.CollegeofFood,XuzhouEngineeringUniversity,Xuzhou221008,China;2.NanjingIndustryUniversity,Nanjing210009,China) Abstract:Inthispaper,NanometerTiOphotocatalyticisusedtopre-processorganophosphoruspesticideresidues.Spectrophotometry 2 methodisusedtodeterminethecontentandcomparedwiththestandardmethod,andthenthebestexperimentalconditionisdefined.24 kindsoforganophosphorouspesticidesareselectedanddegradedbyTiOphotocatalysis,andafterdegradation,thecontentofphosphorousis 2 tested.Comparedwiththestandardmethod,thisnewmethodattainssuchresultthatthedetectionrateoftotalphosphorousisover95%,the -3 -1 -3 · detectionlimit2.10×10mgL,andthestandarddeviation2.86×10.Alsothesamedegradationeffectisachievedinthismethod,whichis furtherverifiedbyUVscanninganalysis.Inaddition,itiseasytorealizeinstrumentationwhichmakespreparationfordesigningandre- searchingontheon-linemonitoringinstrumentoftotalphosphorous. Keywords:organophosphorouspesticide;photocatalysis;NanometerTiO;spectrophotometry;totalphosphorus;pre-proce